
Chemistry (OER)
19th Edition
ISBN: 9781947172623
Author: OpenStax
Publisher: OpenStax College
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Textbook Question
Chapter 13, Problem 26E
Covert the values of Kc to the values of KP or the values of Kp to values of Kc.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
2NH3 (g) = N2 (g) +3H₂
—N2 (g) AGº = 34. kJ
Now suppose a reaction vessel is filled with 4.19 atm of ammonia (NH3) and 9.94 atm of nitrogen (N2) at 378. °C. Answer the following questions about this
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Identifying the major species in weak acid or weak base equilibria
The preparations of two aqueous solutions are described in the table below. For each solution, write the chemical formulas of the major species present at
equilibrium. You can leave out water itself.
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Using reaction free energy to predict equilibrium composition
Consider the following equilibrium:
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Now suppose a reaction vessel is filled with 1.68 atm of dinitrogen tetroxide (N204) at 148. °C. Answer the following questions about this system:
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Under these conditions, will the pressure of N2O4 tend to rise or fall?
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In other words, if you said the pressure of N2O4 will tend to rise, can that
be changed to a tendency to fall by adding NO2? Similarly, if you said the
pressure of N2O4 will tend to fall, can that be changed to a tendency to
rise by adding NO2?
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Chapter 13 Solutions
Chemistry (OER)
Ch. 13 - What does it mean to describe a reaction as...Ch. 13 - When writing an equation, how is a reversible...Ch. 13 - If a reaction is reversible, when can it be said...Ch. 13 - Is a system at equilibrium if the rate constants...Ch. 13 - If the concentrations of products and reactants...Ch. 13 - Explain why there may be an infinite number of...Ch. 13 - Explain why an equilibrium between Br2(l) and...Ch. 13 - If you observe the following reaction at...Ch. 13 - Among the solubility rules previously discussed is...Ch. 13 - Among the solubility rules previously discussed is...
Ch. 13 - Benzene is one of the compounds used as octane...Ch. 13 - Show that the complete chemical equation, the...Ch. 13 - For a titration to be effective, the reaction must...Ch. 13 - For a precipitation reaction to be useful in a...Ch. 13 - Write the mathematical expression for the reaction...Ch. 13 - Write the mathematical expression for the reaction...Ch. 13 - The initial concentrations or pressures of...Ch. 13 - The initial concentrations or pressures of...Ch. 13 - The following reaction has KP=4.50105 at 720 K....Ch. 13 - Determine if the following system is at...Ch. 13 - Which of the systems described in Exercise 13.15...Ch. 13 - Which of the systems described in Exercise 13.16...Ch. 13 - For which of the reactions in Exercise 13.15 does...Ch. 13 - For which of the reactions in Exercise 13.16 does...Ch. 13 - Convert the values of KC to values of KP to the...Ch. 13 - Covert the values of Kc to the values of KP or the...Ch. 13 - What is the value of the equilibrium constant...Ch. 13 - Write the expression of the reaction quotient for...Ch. 13 - Write the reaction quotient expression for the...Ch. 13 - What is the approximate value of the equilibrium...Ch. 13 - The following equation represents a reversible...Ch. 13 - Explain how to recognize the conditions under...Ch. 13 - What property of a reaction can we use to predict...Ch. 13 - What would happen to the color of the solution in...Ch. 13 - The following reaction occurs when a burner on a...Ch. 13 - A necessary step in the manufacture of sulfuric...Ch. 13 - Suggest four ways in which the concentration of...Ch. 13 - Suggest four ways in which the concentration of...Ch. 13 - How will an increase in temperature affect each of...Ch. 13 - How will an increase in temperature affect each of...Ch. 13 - Water gas is a 1:1 mixture of carbon monoxide and...Ch. 13 - Nitrogen and oxygen react at high temperatures....Ch. 13 - Water gas, a mixture of H2 and CO, is an important...Ch. 13 - Pure iron metal can be produced by the reduction...Ch. 13 - Ammonia is a weak base that reacts with water...Ch. 13 - Acetic acid is a weak acid that reacts with water...Ch. 13 - Suggest two ways in which the equilibrium...Ch. 13 - How can the pressure of water vapor be increased...Ch. 13 - Additional solid silver sulfate, a slightly...Ch. 13 - The amino acid alanine has two isomers, -alanine...Ch. 13 - A reaction is represented by this equation:...Ch. 13 - A reaction is represented by this equation:...Ch. 13 - What is the value of the equilibrium constant at...Ch. 13 - Hydrogen is prepared commercially by the reaction...Ch. 13 - A 0.72-m01 sample of PCl5 is put into a 1.00-L...Ch. 13 - At 1 atm and 25 C, NO2 with an initial...Ch. 13 - Calculate the value of the equilibrium constant Kp...Ch. 13 - When heated, iodine vapor dissociates according to...Ch. 13 - A sample of ammonium chloride was heated in a...Ch. 13 - At a temperature of 60 C, the vapor pressure of...Ch. 13 - Complete the changes in concentrations (or...Ch. 13 - Complete the changes in concentrations (or...Ch. 13 - Why are there no changes specified for Ni in...Ch. 13 - Why are there no changes specified for NH4HS in...Ch. 13 - Analysis of the gases in a sealed reaction vessel...Ch. 13 - Calculate the number of moles of HI that are at...Ch. 13 - What is the pressure of BrCl in an equilibrium...Ch. 13 - What is the pressure of CO2 in a mixture at...Ch. 13 - Cobalt metal can be prepared by reducing cobalt...Ch. 13 - Carbon reacts with water vapor at elevated...Ch. 13 - Sodium sulfate 10-hydrate, Na2SO410H2O, dehydrates...Ch. 13 - Calcium Chloride 6-hydrate, CaCl26H2O, dehydrates...Ch. 13 - A student solved the following problem and found...Ch. 13 - A student solved the following problem and found...Ch. 13 - Assume that the change in concentration of N2O4 is...Ch. 13 - Assume that the change in concentration of COCI2...Ch. 13 - Assume that the change in pressure of H2S is small...Ch. 13 - What are all concentrations after a mixture that...Ch. 13 - What are the concentrations of PCl5, PCl3, and Cl2...Ch. 13 - Calculate the pressures of all species at...Ch. 13 - Calculate the equilibrium concentrations of NO,...Ch. 13 - Calculate the equilibrium concentrations that...Ch. 13 - One of the important reactions in the formation of...Ch. 13 - Calculate the pressures of NO, Cl2, and NOCI in an...Ch. 13 - Calculate the number of grams of HI that are at...Ch. 13 - Butane exists as two isomers, n -butane and...Ch. 13 - What is the minimum mass of CaCO3 required to...Ch. 13 - The equilibrium constant (Kc) for this reaction is...Ch. 13 - At 25 C and at 1 atm, the partial pressures in an...Ch. 13 - In a 3.0-L vessel, the following equilibrium...Ch. 13 - The equilibrium constant (Kc) for this reaction is...Ch. 13 - Antimony pentachloride decomposes according to...Ch. 13 - Consider the reaction between H2 and O2 at 1000...Ch. 13 - An equilibrium is established according to the...Ch. 13 - Consider the equilibrium...Ch. 13 - The binding of oxygen by hemoglobin (Hb), giving...Ch. 13 - The hydrolysis of the sugar sucrose to the sugars...Ch. 13 - 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