EBK PHYSICAL UNIVERSE
15th Edition
ISBN: 9780100255036
Author: KRAUSKOPF
Publisher: YUZU
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Textbook Question
Chapter 13, Problem 25E
What is the difference between aromatic and aliphatic compounds?
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Pure membranes of dipalmitoyl lecithin phospholipids are models of biological membranes. They melt
= 41°C. Reversible melting experiments indicate that
at Tm
AHm=37.7 kJ mol-1. Calculate:
A. The entropy of melting, ASm-
B. The Gibbs free energy of melting, AGm-
C. Does the membrane become more or less ordered upon melting?
D. There are 32 rotatable CH2
CH2 bonds in each molecule that can rotate more freely if the
membrane melts. What is the increase in multiplicity on melting a mole of bonds?
5. Heat capacity often has a temperature dependence for real molecules, particularly if
you go over a large temperature range. The heat capacity for liquid n-butane can be
fit to the equation
Cp(T) = a + bT
where a = 100 J K₁₁ mol¹ and b = 0.1067 J K² mol¹ from its freezing point (T = 140 K)
to its boiling point (T₁ = 270 K).
A. Compute AH for heating butane from 170 K to 270 K.
B. Compute AS for the same temperature range.
4. How much energy must be transferred as heat to cause the quasi-static isothermal
expansion of one mole of an ideal gas at 300 K from PA = 1 bar to PB = 0.5 bar?
A. What is VA?
B. What is VB?
C. What is AU for the process?
D. What is AH for the process?
E. What is AS for the process?
Chapter 13 Solutions
EBK PHYSICAL UNIVERSE
Ch. 13 - Prob. 1MCCh. 13 - Prob. 2MCCh. 13 - Prob. 3MCCh. 13 - Prob. 4MCCh. 13 - As a class, the alkanes are a. highly reactive b....Ch. 13 - Prob. 6MCCh. 13 - Gasoline is a mixture of a. alkanes b. isomers of...Ch. 13 - Prob. 8MCCh. 13 - Unsaturated hydrocarbon molecules are...Ch. 13 - Prob. 10MC
Ch. 13 - Prob. 11MCCh. 13 - Prob. 12MCCh. 13 - Prob. 13MCCh. 13 - Prob. 14MCCh. 13 - Prob. 15MCCh. 13 - Prob. 16MCCh. 13 - Prob. 17MCCh. 13 - Prob. 18MCCh. 13 - Prob. 19MCCh. 13 - Prob. 20MCCh. 13 - Prob. 21MCCh. 13 - Prob. 22MCCh. 13 - Living cells consist mainly of a. carbohydrates b....Ch. 13 - Prob. 24MCCh. 13 - Prob. 25MCCh. 13 - Photosynthesis produces a. carbohydrates b....Ch. 13 - Prob. 27MCCh. 13 - Prob. 28MCCh. 13 - Prob. 29MCCh. 13 - Prob. 30MCCh. 13 - Prob. 31MCCh. 13 - Lipids are synthesized in plants and animals from...Ch. 13 - Prob. 33MCCh. 13 - Prob. 34MCCh. 13 - Proteins consist of combinations of a. amino acids...Ch. 13 - The number of amino acids important to life is a....Ch. 13 - Prob. 37MCCh. 13 - Prob. 38MCCh. 13 - Prob. 39MCCh. 13 - Prob. 40MCCh. 13 - Each three-nucleotide group in a DNA molecule...Ch. 13 - DNA is involved in which one or more of the...Ch. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - What is the principal bonding mechanism in organic...Ch. 13 - How can the different alkanes in petroleum be...Ch. 13 - Prob. 5ECh. 13 - Why are structural formulas more important in...Ch. 13 - The isomers of a compound have the same chemical...Ch. 13 - Distinguish between unsaturated and saturated...Ch. 13 - How many electrons are shared in a double bond...Ch. 13 - What kind of carbon-carbon bonds are found in...Ch. 13 - How many covalent bonds are present between the...Ch. 13 - In general, how do the reactivities of hydrocarbon...Ch. 13 - Prob. 13ECh. 13 - The alkanes of Sec. 13.2 are saturated...Ch. 13 - The structural formula of propane is given in Sec....Ch. 13 - Why does this structural formula not represent an...Ch. 13 - Why does this structural formula not represent an...Ch. 13 - Prob. 18ECh. 13 - Is it possible for a molecule with the formula...Ch. 13 - Is it possible for a molecule with the formula...Ch. 13 - Is it possible for a molecule with the formula...Ch. 13 - Each molecule of butyne, C4H6, has a triple bond...Ch. 13 - Each molecule of butene, C4H8, has a double bond...Ch. 13 - Prob. 24ECh. 13 - What is the difference between aromatic and...Ch. 13 - Why are all aromatic compounds unsaturated?Ch. 13 - The carbon atoms in normal hexane, C6H14, form a...Ch. 13 - Prob. 28ECh. 13 - When sugar undergoes fermentation to produce...Ch. 13 - To what class of organic compounds does the...Ch. 13 - To what class of organic compounds does the...Ch. 13 - What have the compounds in each of these pairs in...Ch. 13 - What have the compounds in each of these pairs in...Ch. 13 - Which of the following (a) dissolve in water, (b)...Ch. 13 - Compare the properties of a simple ester, for...Ch. 13 - Why do you think the compound whose structure is...Ch. 13 - Prob. 37ECh. 13 - Use structural formulas to show the reaction...Ch. 13 - Give structural formulas for the two isomeric...Ch. 13 - Prob. 40ECh. 13 - The structural formula of acetone is shown in...Ch. 13 - Use structural formulas to show the reaction...Ch. 13 - (a) Give structural formulas for the three isomers...Ch. 13 - Prob. 44ECh. 13 - How does a plant obtain its carbohydrates and...Ch. 13 - What are the products of the oxidation of glucose?...Ch. 13 - What is believed to be the origin of atmospheric...Ch. 13 - The ultimate source of the energy in food is the...Ch. 13 - Why are unsaturated fats liquid at room...Ch. 13 - Why do plants need nitrogen? Why can they not use...Ch. 13 - What are the basic structural units of proteins?...Ch. 13 - How many letters are there in the genetic code by...Ch. 13 - What change in a gene is involved in a mutation?...Ch. 13 - To which class of organic compounds do most of the...
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