
Concept explainers
(a)
Interpretation:
The electron-pair geometry for the nitrogen atom in
Concept introduction:
The electron pairs in Lewis diagrams repel each other in real molecule and thus, they distribute themselves in positions around the central atoms which are far away from one another. This arrangement of electron pairs is called electron-pair geometry. The electron pairs may be shared in covalent bond, or they may be lone pairs.
(b)
Interpretation:
The molecular geometry prdicted by the valence shell electron-pair repulsion theory for the nitrogen atom in the molecule
Concept introduction:
Molecular geometry is the precise term that is used to describe the shape of molecules and arrangement of atoms around the central atom. The molecular geometry of a molecule is predicted by valence shell electron-pair repulsion theory or in short VSEPR theory. VSEPR theory applies to substances in which a second period element is bonded to two, three, four, or other atoms.

Want to see the full answer?
Check out a sample textbook solution
Chapter 13 Solutions
Bundle: Introductory Chemistry: An Active Learning Approach, 6th + LMS Integrated for OWLv2, 4 terms (24 months) Printed Access Card
- Primary, Secondary, and Tertiary Alcohols O-H O-H O-H R₁-C-H R₁-C-H R₁-C-R₁ H R₂ R₂ Primary Alcohol Secondary Alcohol ChemistryLearner.com R stands for Carbon group like ethyl methyl propyl Tertiary Alcohol If 1 carbon group with two H attached to alcoholic carbon, then primary If 2 carbon group and 1 H are attached to alcoholic carbon, then secondary IF 3 carbon group and no H attach to alcoholic carbon then tertiary. The bottom line Starting "Weak" oxidant material PCC, DMP, Swern, etc Primary alcohol Aldehyde OH Secondary alcohol Ketone OH "Strong" oxidant KMnO4, H₂CrO4 (or equivalent) OH Carboxylic acid 요 Ketone No reaction No reaction Tertiary alcohol 1. Is ethanol a primary, secondary, or tertiary alcohol? Write out the structures of ethanol and any oxidation products of ethanol. If there is more than one oxidation product, give the structure of each of the products. 2. Is 2-propanol a primary, secondary, or tertiary alcohol? Write out the structures of 2-propanol and any…arrow_forwardFormulate the reaction: Naphthalene with CrO3 in acetic acid at 25ºCarrow_forwardComplete the reaction hand written pleasearrow_forward
- Using the Nernst equation to calculate nonstandard cell voltage A galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction: 3+ 3Cu²+ (aq) +2Al(s) → 3 Cu(s)+2A1³* (aq) 2+ Suppose the cell is prepared with 5.29 M Cu in one half-cell and 2.49 M A1³+ in the other. Calculate the cell voltage under these conditions. Round your answer to 3 significant digits. x10 μ ☑ 00. 18 Ar Иarrow_forwardPlease help me solve this homework problemarrow_forwardPlease help me answer this homework questionarrow_forward
- Calculating standard reaction free energy from standard reduction... Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy AG° for the following redox reaction. Be sure your answer has the correct number of significant digits. 3+ H2(g)+2OH¯ (aq) + 2Fe³+ (aq) → 2H₂O (1)+2Fe²+ (aq) 0 kJ x10 Х ? olo 18 Ararrow_forwardCalculating the pH of a weak base titrated with a strong acid An analytical chemist is titrating 184.2 mL of a 0.7800M solution of dimethylamine ((CH3) NH with a 0.3000M solution of HClO4. The pK₁ of dimethylamine is 3.27. Calculate the pH of the base solution after the chemist has added 424.1 mL of the HClO solution to it. 2 4 Note for advanced students: you may assume the final volume equals the initial volume of the solution plus the volume of HClO 4 solution added. Round your answer to 2 decimal places. pH = ☐ ☑ ? 000 18 Ar 1 Barrow_forwardUsing the Nernst equation to calculate nonstandard cell voltage A galvanic cell at a temperature of 25.0 °C is powered by the following redox reaction: MnO2 (s)+4H* (aq)+2Cr²+ (aq) → Mn²+ (aq)+2H₂O (1)+2Cr³+ (aq) + 2+ 2+ 3+ Suppose the cell is prepared with 7.44 M H* and 0.485 M Cr²+ in one half-cell and 7.92 M Mn² and 3.73 M Cr³+ in the other. Calculate the cell voltage under these conditions. Round your answer to 3 significant digits. ☐ x10 μ Х 5 ? 000 日。arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningIntroductory Chemistry: An Active Learning Approa...ChemistryISBN:9781305079250Author:Mark S. Cracolice, Ed PetersPublisher:Cengage Learning


