EBK CHEMISTRY
EBK CHEMISTRY
1st Edition
ISBN: 9780133888584
Author: Tro
Publisher: VST
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Chapter 13, Problem 23E
Interpretation Introduction

(a)

Interpretation:

Sulfur belongs to group 16 of the periodic table, along with O,Se and Te . The element has an atomic number of 16 an atomic mass of 32, four oxidation states (2+2,+4 and +6)

Sulfur has three allotropes: Rhombic, Monoclinic and amorphous.

Sulfur is a non- metal which exists in different crystal structure known as allotropes. The stable form at room temperature is called rhombic sulfur and when this is heated slowly above about 95C it converts into monoclinic sulfur.

EBK CHEMISTRY, Chapter 13, Problem 23E , additional homework tip  1

Only difference between the rhombic and monoclinic types is the arrangement of the molecules in space.

Concept introduction:

Phase diagram represent change in state of substance with change in pressure and temperature.

There are some common line between solid state, liquid state and gaseous state. The line are known as sublimation curve common line between solid state and gaseous state condensation curve (common region between liquid and gas) and meeting curve (common region between solid and liquid state)

EBK CHEMISTRY, Chapter 13, Problem 23E , additional homework tip  2

Generic phase diagram and conversion between states

To determine:

Consider the phase diagram for sulfur shown here. The rhombic and monoclinic are two solid with different structures.

a. The pressure below which solid sulfur sublimes

EBK CHEMISTRY, Chapter 13, Problem 23E , additional homework tip  3

Interpretation Introduction

(b)

Interpretation:

Sulfur belongs to group 16 of the periodic table, along with O,Se and Te . The element has an atomic number of 16 and atomic mass of 32, four oxidation states (2+2,+4 and +6)

Sulfur has three allotropes: Rhombic, Monoclinic and amorphous (no shape plastic).

Sulfur is a non- metal which exists is different crystal structure known as allotropes. The stable form at room temperature is called rhombic sulfur and when this is heated slowly above about 95C it converts into monoclinic sulfur.

EBK CHEMISTRY, Chapter 13, Problem 23E , additional homework tip  4

Only difference between the rhombic and monoclinic types is the arrangement of the molecules in space.

Concept Interdiction:

Phase diagram represents change in state of substance with change in pressure and temperature.

There are some common line between solid state, liquid state and gaseous state. The line are known as sublimation curve common line between solid state and gaseous state condensation curve (common region between liquid and gas) and melting curve (common region between solid and liquid state)

EBK CHEMISTRY, Chapter 13, Problem 23E , additional homework tip  5

Generic phase diagram and conversion between states

To determine: between the two solid states of sulfur which is denser

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Chapter 13 Solutions

EBK CHEMISTRY

Ch. 13 - What is a phase diagram?Ch. 13 - Draw a generic phase diagram and label its...Ch. 13 - What is the significance of crossing a line in a...Ch. 13 - What is graphene? Why is graphene unique?Ch. 13 - Prob. 5ECh. 13 - What is a crystalline lattice? How is the lattice...Ch. 13 - Prob. 7ECh. 13 - Prob. 8ECh. 13 - What is the difference between hexagonal closest...Ch. 13 - What are the three basic types of solids and the...Ch. 13 - Prob. 11ECh. 13 - What kinds of forces hold each of the three basic...Ch. 13 - Prob. 13ECh. 13 - Prob. 14ECh. 13 - Prob. 15ECh. 13 - Prob. 16ECh. 13 - Prob. 17ECh. 13 - Prob. 18ECh. 13 - Prob. 19ECh. 13 - Consider the phase diagram for iodine shown here....Ch. 13 - Prob. 21ECh. 13 - Prob. 22ECh. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Prob. 25ECh. 13 - An X-ray beam of unknown wavelength is diffracted...Ch. 13 - Prob. 27ECh. 13 - Determine the coordination number for each...Ch. 13 - Prob. 29ECh. 13 - Molybdenum crystallizes with the body-centred unit...Ch. 13 - Prob. 31ECh. 13 - An atom has a radius of 142 pm and crystallizes in...Ch. 13 - Rhodium has a density of 12.41 g / cm3 and...Ch. 13 - Barium has a density of 3.59 g/cm3 and...Ch. 13 - Prob. 35ECh. 13 - Palladium crystallizes with a face-centered cubic...Ch. 13 - Prob. 37ECh. 13 - Identify each solid as molecular, ionic, or...Ch. 13 - Which solid has the highest melting point? Why?...Ch. 13 - Which solid has the highest melting point? Why?...Ch. 13 - Which solid in each pair has the higher melting...Ch. 13 - Which solid in each pair has the higher melting...Ch. 13 - Prob. 43ECh. 13 - Prob. 44ECh. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - The unit cells for cesium chloride and barium(ll)...Ch. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - Prob. 54ECh. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - The density of an unknown metal is 12.3 g/cm3 and...Ch. 13 - Prob. 59ECh. 13 - Consider a planet where the pressure of the...Ch. 13 - An unknown metal is found to have a density of...Ch. 13 - Prob. 62ECh. 13 - Potassium chloride crystallizes in the rock salt...Ch. 13 - Calculate the fraction of empty space in cubic...Ch. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67E
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