Elements Of Physical Chemistry
7th Edition
ISBN: 9780198796701
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 13, Problem 13B.6E
Interpretation Introduction
Interpretation:
From the observation of a single broad peak for N-aetylbenzoxazene, the lifetime of interconversion of its isomers has to be calculated.
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k₁
Given the reaction R₂
R + R, indicate
k-1
(A). the rate law with respect to R2:
(B). the rate law with respect to R:
d[R₂]
dt
d[R]
dt
Given the reaction R+ Q → P, indicate
(A). the rate law with respect to P:
(B). the rate law with respect to R:
(C). the rate law with respect to Q:
d[P]
dt
d[R]
dt
d[Q]
dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
Chapter 13 Solutions
Elements Of Physical Chemistry
Ch. 13 - Prob. 13A.1STCh. 13 - Prob. 13A.2STCh. 13 - Prob. 13B.1STCh. 13 - Prob. 13B.2STCh. 13 - Prob. 13B.3STCh. 13 - Prob. 13B.4STCh. 13 - Prob. 13B.5STCh. 13 - Prob. 13C.1STCh. 13 - Prob. 13C.2STCh. 13 - Prob. 13C.3ST
Ch. 13 - Prob. 13A.1ECh. 13 - Prob. 13A.2ECh. 13 - Prob. 13A.3ECh. 13 - Prob. 13A.4ECh. 13 - Prob. 13A.5ECh. 13 - Prob. 13A.6ECh. 13 - Prob. 13B.1ECh. 13 - Prob. 13B.2ECh. 13 - Prob. 13B.3ECh. 13 - Prob. 13B.4ECh. 13 - Prob. 13B.5ECh. 13 - Prob. 13B.6ECh. 13 - Prob. 13C.1ECh. 13 - Prob. 13C.2ECh. 13 - Prob. 13C.3ECh. 13 - Prob. 13C.4ECh. 13 - Prob. 13C.5ECh. 13 - Prob. 13C.6ECh. 13 - Prob. 13C.7ECh. 13 - Prob. 13C.8ECh. 13 - Prob. 13.1DQCh. 13 - Prob. 13.2DQCh. 13 - Prob. 13.3DQCh. 13 - Prob. 13.4DQCh. 13 - Prob. 13.5PCh. 13 - Prob. 13.6PCh. 13 - Prob. 13.7PCh. 13 - Prob. 13.11PCh. 13 - Prob. 13.12PCh. 13 - Prob. 13.13P
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