The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn. Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Draw all the alkyl halides with molecular formula C 5H 11Cl formed when pentane (CH 3CH 2CH 2CH 2CH 3) is heated with Cl 2.

1,4-Pentadiene (CH2=CH-CH2-CH=CH2) is a liquid at room temperature and has a density of 0.66 g/mL and molar mass of 68.12 g/mol. In a laboratory experiment, 3.80 mL of this compound was treated with 4.80 mL of conc. H2SO4 (100% w/w; molar mass 98.08 g/mol). Note that the density of conc. H2SO4 is 1.84 g/mL. The resulting sulfate ester was then treated with 1.20 mL of water (molar mass 18.02 g/mol) affording, after work- up, 2,4-pentanediol (molar mass 104.15 g/mol) as the crude product. The crude product was then purified by simple distillation, which yielded 2.00 g of pure product. What is the theoretical yield of 2,4-pentanediol expressed in grams? Show calculations. What is the percentage yield of pure 2,4-pentanediol?

1,4-Pentadiene (CH2=CH-CH2-CH=CH2) is a liquid at room temperature and has a density of 0.66 g/mL and molar mass of 68.12 g/mol. In a laboratory experiment, 3.80 mL of this compound was treated with 4.80 mL of conc. H2SO4 (100% w/w; molar mass 98.08 g/mol). Note that the density of conc. H2SO4 is 1.84 g/mL. The resulting sulfate ester was then treated with 1.20 mL of water (molar mass 18.02 g/mol) affording, after work- up, 2,4-pentanediol (molar mass 104.15 g/mol) as the crude product. The crude product was then purified by simple distillation, which yielded 2.00 g of pure product. a. Provide a balanced chemical equation to show the reaction between 1,4-pentadiene and sulfuric acid. Do not use molecular formulas in the chemical equation except for sulfuric acid. b. What reactant is the limiting reagent in this chemical equation? Show calculations to support your answer.

Answer 2

Question

Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Answer 3

Question

Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Answer 4

Question

Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Answer 5

Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

Answer 6

Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

Answer 7

Chapter 13, Problem 13.53P

Interpretation Introduction

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 13 - What is the mass of the molecular ion formed from...Ch. 13 - Prob. 13.2P Ch. 13 - Use the following information to propose a...Ch. 13 - Prob. 13.4P Ch. 13 - What molecular ions would you expect for the...Ch. 13 - The mass spectrum of 2,3-dimethylpentane also...Ch. 13 - The base peak in the mass spectrum of 2, 2,...Ch. 13 - (a) What mass spectral fragments are formed by ...Ch. 13 - What cations are formed in the mass spectrometer...Ch. 13 - The low-resolution mass spectrum of an unknown...

The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn. Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

Solution Summary: The author explains that IR spectroscopy is used to identify the functional group present in a compound.

Concept explainers

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Chapter 13 Solutions

The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn. Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

Solution Summary: The author explains that IR spectroscopy is used to identify the functional group present in a compound.

Concept explainers

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn. Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.

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Chapter 13 Solutions

Interpretation: The structure for compound B is to be proposed. The stepwise mechanism that accounts for its formation is to be drawn.

Concept introduction: IR spectroscopy is used to identify the functional group present in a compound. Each and every bond vibrates at a characteristic frequency.