AVC LOOSELEAF CHEMISTRY W/CONNECT 2 SEM
13th Edition
ISBN: 9781260987164
Author: Chang
Publisher: MCG CUSTOM
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Textbook Question
Chapter 13, Problem 13.51QP
Determine the molecularity and write the rate law for each of the following elementary steps:
- (a) X → products
- (b) X + Y → products
- (c) X + Y + Z → products
- (d) X + X → products
- (e) X + 2Y → products
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Draw the epoxide formed when the following alkene is treated with mCPBA. Click the "draw
structure" button to launch the drawing utility.
draw structure ...
Rank each of the following substituted benzene molecules in order of which will react fastest (1) to slowest (4) by electrophilic
aromatic substitution.
Explanation
Check
CF3
(Choose one)
OH
(Choose one)
H
(Choose one)
(Choose one)
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Identifying electron-donating and electron-withdrawing effects
For each of the substituted benzene molecules below, determine the inductive and resonance effects the substituent will have on the
benzene ring, as well as the overall electron-density of the ring compared to unsubstituted benzene.
Molecule
Inductive Effects
Resonance Effects
Overall Electron-Density
CF3
O donating
O donating
O electron-rich
O withdrawing
withdrawing
O no inductive effects
O no resonance effects
O electron-deficient
O similar to benzene
OCH3
Explanation
Check
O donating
O donating
○ withdrawing
withdrawing
O no inductive effects
no resonance effects
electron-rich
electron-deficient
O similar to benzene
Х
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Chapter 13 Solutions
AVC LOOSELEAF CHEMISTRY W/CONNECT 2 SEM
Ch. 13.1 - Write the rate expressions for the following...Ch. 13.1 - Consider the reaction 4PH3(g)P4(g)+6H2(g) Suppose...Ch. 13.1 - Write a balanced equation for a gas-phase reaction...Ch. 13.1 - Write the rate expression for the following...Ch. 13.1 - For the same reaction, 2A+BC+2D what is the rate...Ch. 13.2 - The reaction of peroxydisulfate ion (S2O82) with...Ch. 13.2 - For the reaction A + 2B C + 2D, use the following...Ch. 13.2 - The relative rates of the reaction 2A + B ...Ch. 13.3 - The reaction 2A B is first order in A with a rate...Ch. 13.3 - Ethyl iodide (C2H5I) decomposes at a certain...
Ch. 13.3 - Calculate the half-life of the decomposition of...Ch. 13.3 - The reaction 2A B is second order with a rate...Ch. 13.3 - Consider the first-order reaction A B in which A...Ch. 13.3 - Consider the reaction A products. The half-life...Ch. 13.3 - Consider the first-order reaction A products. The...Ch. 13.3 - What is the initial concentration of a reactant in...Ch. 13.4 - The second-order rate constant for the...Ch. 13.4 - The first-order rate constant for the reaction of...Ch. 13.4 - What is the activation energy of a particular...Ch. 13.4 - Prob. 2RCFCh. 13.5 - The reaction between NO2 and CO to produce NO and...Ch. 13.5 - The rate law for the reaction H2 + 2IBr I2 + 2HBr...Ch. 13.5 - For the reaction between NO and O2, the following...Ch. 13.6 - Which of the following is false regarding...Ch. 13 - What is meant by the rate of a chemical reaction?...Ch. 13 - Distinguish between average rate and instantaneous...Ch. 13 - Prob. 13.3QPCh. 13 - Can you suggest two reactions that are very slow...Ch. 13 - Write the reaction rate expressions for the...Ch. 13 - Write the reaction rate expressions for the...Ch. 13 - Consider the reaction 2NO(g)+O2(g)2NO2(g) Suppose...Ch. 13 - Consider the reaction N2(g)+3H2(g)2NH3(g) Suppose...Ch. 13 - Explain what is meant by the rate law of a...Ch. 13 - What are the units for the rate constants of...Ch. 13 - Consider the zero-order reaction: A product. (a)...Ch. 13 - On which of the following properties does the rate...Ch. 13 - The rate law for the reaction...Ch. 13 - Use the data in Table 13.2 to calculate the rate...Ch. 13 - Consider the reaction A+Bproducts From the...Ch. 13 - Consider the reaction X+YZ From the following...Ch. 13 - Determine the overall orders of the reactions to...Ch. 13 - Consider the reaction AB The rate of the reaction...Ch. 13 - Cyclobutane decomposes to ethylene according to...Ch. 13 - The following gas-phase reaction was studied at...Ch. 13 - Prob. 13.21QPCh. 13 - Prob. 13.22QPCh. 13 - Prob. 13.23QPCh. 13 - Prob. 13.24QPCh. 13 - What is the half-life of a compound if 75 percent...Ch. 13 - The thermal decomposition of phosphine (PH3) into...Ch. 13 - The rate constant for the second-order reaction...Ch. 13 - The rate constant for the second-order reaction...Ch. 13 - Consider the first-order reaction A B shown here....Ch. 13 - The reaction X Y shown here follows first-order...Ch. 13 - Define activation energy. What role does...Ch. 13 - Prob. 13.32QPCh. 13 - Prob. 13.33QPCh. 13 - Prob. 13.34QPCh. 13 - Sketch a potential energy versus reaction progress...Ch. 13 - Prob. 13.36QPCh. 13 - The diagram in (a) shows the plots of ln k versus...Ch. 13 - Given the same reactant concentrations, the...Ch. 13 - Some reactions are described as parallel in that...Ch. 13 - Variation of the rate constant with temperature...Ch. 13 - For the reaction NO(g)+O3(g)NO2(g)+O2(g) the...Ch. 13 - The rate constant of a first-order reaction is...Ch. 13 - The rate constants of some reactions double with...Ch. 13 - Prob. 13.44QPCh. 13 - Consider the second-order reaction...Ch. 13 - The rate at which tree crickets chirp is 2.0 102...Ch. 13 - Prob. 13.47QPCh. 13 - What do we mean by the mechanism of a reaction?...Ch. 13 - Classify each of the following elementary steps as...Ch. 13 - Reactions can be classified as unimolecular,...Ch. 13 - Determine the molecularity and write the rate law...Ch. 13 - What is the rate-determining step of a reaction?...Ch. 13 - The equation for the combustion of ethane (C2H6)...Ch. 13 - Specify which of the following species cannot be...Ch. 13 - The rate law for the reaction...Ch. 13 - For the reaction X2 + Y + Z XY + XZ it is found...Ch. 13 - Prob. 13.57QPCh. 13 - The rate law for the reaction...Ch. 13 - How does a catalyst increase the rate of a...Ch. 13 - What are the characteristics of a catalyst?Ch. 13 - A certain reaction is known to proceed slowly at...Ch. 13 - Distinguish between homogeneous catalysis and...Ch. 13 - Prob. 13.63QPCh. 13 - The concentrations of enzymes in cells are usually...Ch. 13 - The diagram shown here represents a two-step...Ch. 13 - Consider the following mechanism for the...Ch. 13 - The following diagrams represent the progress of...Ch. 13 - Prob. 13.68QPCh. 13 - Prob. 13.69QPCh. 13 - List four factors that influence the rate of a...Ch. 13 - Prob. 13.71QPCh. 13 - Prob. 13.72QPCh. 13 - Prob. 13.73QPCh. 13 - The following data were collected for the reaction...Ch. 13 - Prob. 13.75QPCh. 13 - The rate of the reaction...Ch. 13 - Which of the following equations best describes...Ch. 13 - Prob. 13.78QPCh. 13 - The bromination of acetone is acid-catalyzed:...Ch. 13 - The decomposition of N2O to N2 and O2 is a...Ch. 13 - The reaction S2O82+2I2SO42+I2 proceeds slowly in...Ch. 13 - Prob. 13.82QPCh. 13 - The integrated rate law for the zero-order...Ch. 13 - Prob. 13.84QPCh. 13 - Prob. 13.85QPCh. 13 - The diagrams here represent the reaction A + B C...Ch. 13 - Prob. 13.87QPCh. 13 - The rate law for the reaction 2NO2 (g) N2O4(g) is...Ch. 13 - Prob. 13.89QPCh. 13 - Prob. 13.90QPCh. 13 - Briefly comment on the effect of a catalyst on...Ch. 13 - When 6 g of granulated Zn is added to a solution...Ch. 13 - Prob. 13.93QPCh. 13 - A certain first-order reaction is 35.5 percent...Ch. 13 - The decomposition of dinitrogen pentoxide has been...Ch. 13 - The thermal decomposition of N2O5 obeys...Ch. 13 - Prob. 13.97QPCh. 13 - Prob. 13.99QPCh. 13 - Prob. 13.100QPCh. 13 - Prob. 13.101QPCh. 13 - Chlorine oxide (ClO), which plays an important...Ch. 13 - Prob. 13.103QPCh. 13 - Prob. 13.104QPCh. 13 - Prob. 13.105QPCh. 13 - Prob. 13.106QPCh. 13 - Prob. 13.107QPCh. 13 - Prob. 13.108QPCh. 13 - Prob. 13.109QPCh. 13 - Thallium(I) is oxidized by cerium(IV) as follows:...Ch. 13 - Prob. 13.111QPCh. 13 - Prob. 13.112QPCh. 13 - Prob. 13.113QPCh. 13 - Prob. 13.114QPCh. 13 - Strontium-90, a radioactive isotope, is a major...Ch. 13 - Prob. 13.117QPCh. 13 - Consider the following potential energy profile...Ch. 13 - Prob. 13.119QPCh. 13 - Prob. 13.120QPCh. 13 - Prob. 13.121QPCh. 13 - Prob. 13.122QPCh. 13 - Prob. 13.123QPCh. 13 - Prob. 13.124QPCh. 13 - Polyethylene is used in many items, including...Ch. 13 - Prob. 13.126QPCh. 13 - Prob. 13.127QPCh. 13 - Prob. 13.128QPCh. 13 - Prob. 13.129QPCh. 13 - Prob. 13.130QPCh. 13 - Prob. 13.131QPCh. 13 - A gas mixture containing CH3 fragments, C2H6...Ch. 13 - Prob. 13.133QPCh. 13 - The activation energy (Ea) for the reaction...Ch. 13 - The rate constants for the first-order...Ch. 13 - Prob. 13.136QPCh. 13 - An instructor performed a lecture demonstration of...Ch. 13 - Prob. 13.138QPCh. 13 - Is the rate constant (k) of a reaction more...Ch. 13 - Prob. 13.140QPCh. 13 - Prob. 13.141QPCh. 13 - Prob. 13.142QP
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