(a) Interpretation: The structure of a six-carbon hydrocarbon, not an alkene , whose proton NMR spectrum consists of one singlet is to be stated. Concept introduction: Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 1

Question

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 2

Question

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 3

Question

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 4

Question

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

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Answer 5

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 6

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 7

Chapter 13, Problem 13.39AP

Interpretation Introduction

(a)

Interpretation:

The structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The structure of a six-carbon alkene whose proton NMR spectrum consists of one singlet is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The structure of an eight-carbon ether whose proton NMR spectrum consists of one singlet and whose proton-decoupled 13C NMR spectrum consists of two lines is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The structure of a nine-carbon hydrocarbon whose proton NMR spectrum consists of two singlets is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 14

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 15

Interpretation Introduction

(e)

Interpretation:

The structure of a seven-carbon hydrocarbon whose proton NMR spectrum consists of two singlets at δ 0.23 and δ 1.21 and whose proton-decoupled 13C NMR spectrum consists of three absorptions is to be stated.

Concept introduction:

Many nuclei and electrons have spin. Due to this spin magnetic moment arises. The energy of this magnetic moment depends on the orientation of the applied magnetic field. In NMR spectroscopy, every nucleus has a spin. There is an angular momentum related to the spin. The difference between its resonance frequency and that of the reference standard is known as the chemical shift of a nucleus. Tetramethylsilane (TMS) is taken as reference.

Answer 16

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Answer 17

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Answer 18

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Answer 19

Ch. 13 - Prob. 13.1P Ch. 13 - Prob. 13.2P Ch. 13 - Prob. 13.3P Ch. 13 - Prob. 13.4P Ch. 13 - Prob. 13.5P Ch. 13 - Prob. 13.6P Ch. 13 - Prob. 13.7P Ch. 13 - Prob. 13.8P Ch. 13 - Prob. 13.9P Ch. 13 - Prob. 13.10P

Solution Summary: The author explains the structure of a six-carbon hydrocarbon, not an alkene, whose proton NMR spectrum consists of one singlet.

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