Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
3rd Edition
ISBN: 9781305367388
Author: Lawrence S. Brown, Tom Holme
Publisher: Cengage Learning
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Chapter 13, Problem 13.37PAE
Interpretation Introduction
Interpretation:
How we will determine the value of free energy using electrical work and cell potential in an
Concept Introduction: Cell potential is the maximum electrical work done by the electrolytic cell.
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Students have asked these similar questions
5. A solution of sucrose is fermented in a vessel until the evolution of CO2 ceases. Then, the
product solution is analyzed and found to contain, 45% ethanol; 5% acetic acid; and 15%
glycerin by weight.
If the original charge is 500 kg, evaluate;
e. The ratio of sucrose to water in the original charge (wt/wt).
f. Moles of CO2 evolved.
g. Maximum possible amount of ethanol that could be formed.
h. Conversion efficiency.
i. Per cent excess of excess reactant.
Reactions:
Inversion reaction: C12H22O11 + H2O →2C6H12O6
Fermentation reaction: C6H12O6 →→2C2H5OH + 2CO2
Formation of acetic acid and glycerin: C6H12O6 + C2H5OH + H₂O→ CH3COOH + 2C3H8O3
Show work. don't give Ai generated solution. How many carbons and hydrogens are in the structure?
13. (11pts total) Consider the arrows pointing at three different carbon-carbon bonds in the
molecule depicted below.
Bond B
2°C. +2°C. cleavage
Bond A
•CH3 + 26.← Cleavage
2°C. +
Bond C
+3°C•
CH3 2C
Cleavage
E
2°C. 26.
weakest bond
Intact molecule
Strongest 3°C 20.
Gund
Largest
argest
a. (2pts) Which bond between A-C is weakest? Which is strongest? Place answers in
appropriate boxes.
C
Weakest
bond
A
Produces
Most
Bond
Strongest
Bond
Strongest Gund
produces least stable
radicals
Weakest
Stable radical
b. (4pts) Consider the relative stability of all cleavage products that form when bonds A,
B, AND C are homolytically cleaved/broken. Hint: cleavage products of bonds A, B,
and C are all carbon radicals.
i. Which ONE cleavage product is the most stable? A condensed or bond line
representation is fine.
13°C. formed in
bound C
cleavage
ii. Which ONE cleavage product is the least stable? A condensed or bond line
representation is fine.
• CH3
methyl radical
Formed in Gund A Cleavage
c.…
Chapter 13 Solutions
Bundle: Chemistry for Engineering Students, 3rd, Loose-Leaf + OWLv2 with QuickPrep 24-Months Printed Access Card
Ch. 13 - Prob. 1COCh. 13 - Prob. 2COCh. 13 - • write and balance half-reactions for simple...Ch. 13 - Prob. 4COCh. 13 - Prob. 5COCh. 13 - • use standard reduction potentials to predict the...Ch. 13 - • calculate the amount of metal plated, the amount...Ch. 13 - Prob. 8COCh. 13 - Prob. 9COCh. 13 - Prob. 10CO
Ch. 13 - Prob. 13.1PAECh. 13 - Prob. 13.2PAECh. 13 - Prob. 13.3PAECh. 13 - Prob. 13.4PAECh. 13 - For the following oxidationreduction reactions,...Ch. 13 - Prob. 13.6PAECh. 13 - Prob. 13.7PAECh. 13 - Which half-reaction takes place at the anode of an...Ch. 13 - If a salt bridge contains KNO3 as its electrolyte,...Ch. 13 - If a salt bridge contains KNO3 as its electrolyte,...Ch. 13 - The following oxidationreduction reactions are...Ch. 13 - Write a balanced chemical equation for the overall...Ch. 13 - For the reactions in parts (a) and (b) in the...Ch. 13 - Explain why the terms cell potential and...Ch. 13 - How does galvanic corrosion differ from uniform...Ch. 13 - Prob. 13.16PAECh. 13 - A student who has mercury amalgam fillings in some...Ch. 13 - Based on the cell potential measured for the cells...Ch. 13 - Prob. 13.19PAECh. 13 - Four voltaic cells are set up. In each, one...Ch. 13 - Prob. 13.21PAECh. 13 - Explain why a large negative value for the...Ch. 13 - In tables of standard reduction potentials that...Ch. 13 - In the table of standard reduction potentials,...Ch. 13 - Using values from the table of standard reduction...Ch. 13 - Using values from the table of standard reduction...Ch. 13 - One half-cell in a voltaic cell is constructed...Ch. 13 - Four metals, A, B, C, and D, exhibit the following...Ch. 13 - Use the Nernst equation to calculate the cell...Ch. 13 - One half-cell in a voltaic cell is constructed...Ch. 13 - We noted that a tin-plated steel can corrodes more...Ch. 13 - The following half-cells are available: Ag(s);...Ch. 13 - Prob. 13.33PAECh. 13 - Prob. 13.34PAECh. 13 - In May 2000, a concrete pedestrian walkway...Ch. 13 - Prob. 13.36PAECh. 13 - Prob. 13.37PAECh. 13 - Prob. 13.38PAECh. 13 - Calculate the standard free energy change for the...Ch. 13 - Suppose that you cannot find a table of standard...Ch. 13 - Prob. 13.41PAECh. 13 - Which of the following reactions is (are)...Ch. 13 - Consult a table of standard reduction potentials...Ch. 13 - The equilibrium constant for a reaction is 31015...Ch. 13 - Some calculators cannot display results of an...Ch. 13 - Calculate the equilibrium constant for the...Ch. 13 - Use the standard reduction potentials for the...Ch. 13 - Hydrogen peroxide is often stored in the...Ch. 13 - Calculate the equilibrium constant for the redox...Ch. 13 - Prob. 13.50PAECh. 13 - An engineer is assigned to design an...Ch. 13 - A magnesium bar with a mass of 6.0 kg is attached...Ch. 13 - Prob. 13.53PAECh. 13 - Prob. 13.54PAECh. 13 - Prob. 13.55PAECh. 13 - Prob. 13.56PAECh. 13 - Prob. 13.57PAECh. 13 - If you put a 9-volt battery in a smoke detector in...Ch. 13 - If alkaline batteries were not alkaline but rather...Ch. 13 - What would happen to the voltage of an alkaline...Ch. 13 - Battery manufacturers often assess batteries in...Ch. 13 - Prob. 13.62PAECh. 13 - What product forms from the lead components of a...Ch. 13 - Prob. 13.64PAECh. 13 - Prob. 13.65PAECh. 13 - Assume the specifications of a Ni-Cd voltaic cell...Ch. 13 - Prob. 13.67PAECh. 13 - What is the difference between active and passive...Ch. 13 - Prob. 13.69PAECh. 13 - Prob. 13.70PAECh. 13 - Prob. 13.71PAECh. 13 - Prob. 13.72PAECh. 13 - In an electroplating operation, the cell potential...Ch. 13 - Prob. 13.74PAECh. 13 - Prob. 13.75PAECh. 13 - Prob. 13.76PAECh. 13 - Use the Internet to find electroplating companies...Ch. 13 - Prob. 13.78PAECh. 13 - If a current of 15 A is run through an...Ch. 13 - Suppose somebody in a laboratory doesn't quite...Ch. 13 - If a barrel plating run uses 200.0 A for exactly 6...Ch. 13 - An electrical engineer is analyzing an...Ch. 13 - In a copper plating experiment in which copper...Ch. 13 - A metallurgist wants to gold-plate a thin sheet...Ch. 13 - Tin-plated steel is used for "tin" cans. Suppose...Ch. 13 - An electrolysis cell for aluminum production...Ch. 13 - If a plating line that deposits nickel (from NiCl2...Ch. 13 - Prob. 13.88PAECh. 13 - Prob. 13.89PAECh. 13 - A small part with a surface area of 2.62 cm2 is...Ch. 13 - An engineer is designing a mirror for an optical...Ch. 13 - Prob. 13.92PAECh. 13 - Prob. 13.93PAECh. 13 - What characteristic of lithium ions makes it...Ch. 13 - Looking at Figure 13.23, describe how the...Ch. 13 - Prob. 13.96PAECh. 13 - For a voltage-sensitive application, you are...Ch. 13 - Prob. 13.98PAECh. 13 - Prob. 13.99PAECh. 13 - Prob. 13.100PAECh. 13 - Prob. 13.101PAECh. 13 - 13.104 (a) What happens when a current is passed...Ch. 13 - A current is passed through a solution of...Ch. 13 - 13.106 Hydrazine, N2H4 , has been proposed as the...Ch. 13 - Prob. 13.105PAE
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