The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined. Concept introduction: The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

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Answer 1

Question

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.

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Answer 2

Question

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

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Answer 3

Question

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

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Answer 4

Question

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

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Answer 5

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 6

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 7

Chapter 13, Problem 13.34SP

(a)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 14

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 15

(e)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 17

(f)

Interpretation Introduction

Interpretation:

The multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

Concept introduction:

The chemical shift is defined as the difference in parts per million in the absorption spectrum of a particular proton from the absorption position of a reference proton. Tetramethylsilane is taken as the reference proton. Chemical shifts are measured in parts per million and it is dimensionless quantity.

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 13.5A - In a 300-MHz spectrometer, the protons in...Ch. 13.5B - Prob. 13.2P Ch. 13.6 - Determine the number of different kinds of protons...Ch. 13.6 - Prob. 13.4P Ch. 13.7 - Draw the integral trace expected for the NMR...Ch. 13.7 - Prob. 13.6P Ch. 13.8C - Draw the NMR spectra you would expect for the...Ch. 13.8D - Draw the NMR spectra you expect for the following...Ch. 13.8D - a. Assign protons to the peaks in the NMR spectrum...Ch. 13.8D - Prob. 13.10P

Solution Summary: The author explains that the multiplicity and the chemical shifts for each shaded protons in the given compound are to be determined.

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Chapter 13 Solutions