Chemistry: An Atoms-Focused Approach
14th Edition
ISBN: 9780393912340
Author: Thomas R. Gilbert, Rein V. Kirss, Natalie Foster
Publisher: W. W. Norton & Company
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Starting from bromoethane, how could you prepare the following compounds:
a. Ethanol.
b. Acetaldehyde
f. Acetone.
e. 2-Propanol
i. Acetoacetic ester.
d. 2-Bromoacetic acid.
c. Acetic acid
g. Acetamide.
j. Ethylmalonate
k. Gama ketoacid.
h. Ethyl magnesium bromide.
-
The pressure above a pure sample of solid Substance X at 60. °C is raised. At what pressure will the sample melt? Use the phase diagram of X below to find
your answer.
pressure (atm)
02
0.4
solid
Hliquid
gas
0
0
200
400
600
temperature (K)
Note: your answer must be within 0.025 atm of the exact answer to be graded correct.
☐ atm
15. What is the order of decreasing reactivity towards nucleophilic acyl substitution for the
carboxylic acid derivatives? (most reactive first)
0
O
H3C COC CH3 H₂C C N(CH3)2 H3C C OCH3
A.
a.
I, 11, 111,
b.
I, III, IV, II
C.
II, IV, III, I
°
(CH3)2CH C OCH3
IV
d. II, I, III, IV
B. R COCR
0
0
0
13=
RC NH2
RC OR
RC CI
===
IV
a.
I, III, II, IV
b. II, III, I, IV
C.
III, II, I, IV
d. IV, I, III, II
Chapter 13 Solutions
Chemistry: An Atoms-Focused Approach
Ch. 13 - Prob. 13.1VPCh. 13 - Prob. 13.2VPCh. 13 - Prob. 13.3VPCh. 13 - Prob. 13.4VPCh. 13 - Prob. 13.5VPCh. 13 - Prob. 13.6VPCh. 13 - Prob. 13.7VPCh. 13 - Prob. 13.8VPCh. 13 - Prob. 13.9VPCh. 13 - Prob. 13.10VP
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