Quantitative Chemical Analysis
Quantitative Chemical Analysis
9th Edition
ISBN: 9781464135385
Author: Daniel C. Harris
Publisher: W. H. Freeman
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Chapter 13, Problem 13.14P
Interpretation Introduction

Interpretation:

The composition of solution and fraction of iron and Glycine in each of its form and the principal chemistry required for the addition of HCl to obtain pHof 8.50 has to be calculated. The values of pFe,pG and pCl that satisfy the combined charge and mass balances has to be estimated.

Concept introduction:

Davies equation:

The activity coefficient (γ) of ions is given by

logγ=-0.51z2(µ1+µ-0.3µ)where,γ-activitycoefficientofionz-chargeofionµ-ionicstrength

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NH (aq)+CNO (aq) → CO(NH2)2(s) Experiment [NH4] (M) [CNO] (M) Initial rate (M/s) 1 0.014 0.02 0.002 23 0.028 0.02 0.008 0.014 0.01 0.001 Calculate the rate contant for this reaction using the data provided in the table.
2CIO2 + 20H-1 CIO31 + CIO2 + H2O Experiment [CIO2], M [OH-1], M 1 0.0500 0.100 23 2 0.100 0.100 3 0.100 0.0500 Initial Rate, M/s 0.0575 0.230 0.115 ... Given this date, calculate the overall order of this reaction.
2 3 .(be)_[Ɔ+(be)_OI ← (b²)_IƆO+ (be)_I Experiment [1-] M 0.005 [OCI-] 0.005 Initial Rate M/min 0.000275 0.0025 0.005 0.000138 0.0025 0.0025 0.000069 4 0.0025 0.0025 0.000140 Calculate the rate constant of this reaction using the table data.
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