Chapter 13, Problem 13.106QP

(a)

Interpretation Introduction

Interpretation: The information regarding the difference in the thermal and photo thermal decomposition of ${\text{NO}}_2$ is given. The mechanism that is possible for the photodecomposition of ${\text{NO}}_2$ is to be stated.

Concept introduction: According to the rate law the rate of reaction depends on the concentration of reactants that are involved in the reaction. Therefore, for a reaction like $\text{A}\to \text{B}$, the rate law equation is given as,

$\text{Rate}=k{\left[\text{A}\right]}^m$

Where,

• $k$ is the rate constant.
• $m$ is the order of the reaction.

To determine: The rate law equation for the given mechanism.

(b)

Interpretation Introduction

To determine: The rate law equation for the given mechanism.

(c)

Interpretation Introduction

To determine: The rate law equation for the given mechanism.