INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.
6th Edition
ISBN: 9780134845609
Author: Tro
Publisher: PEARSON
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Chapter 13, Problem 10E
Interpretation Introduction

Interpretation:

The formation of rock candy is to be explained.

Concept introduction:

The rock candy utilizes the recrystallization technique for its formation.

This technique employs high temperature in achieving a solute in its pure form.

High temperature increases the solubility of the solute.

The solution is allowed to cool down slowly. The excess amount of solute precipitates out from the solution in the form of crystals.

The impurities are left behind in the solution as the solute precipitates slowly

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

Chapter 13 Solutions

INTRODUCTORY CHEMISTRY-W/SEL.SOLN.MAN.

Ch. 13 - What mass of ethylene glycol (C2H6O6) must be...Ch. 13 - Prob. 1ECh. 13 - Prob. 2ECh. 13 - Prob. 3ECh. 13 - Explain what like dissolves like means.Ch. 13 - What is solubility?Ch. 13 - Describe what happens when additional solute is...Ch. 13 - 7. Explain the difference between a strong...Ch. 13 - 8. How does gas solubility depend on...Ch. 13 - Prob. 9ECh. 13 - Prob. 10ECh. 13 - 11. When you heat water on a stove, bubbles form...Ch. 13 - Prob. 12ECh. 13 - How does gas solubility depend on pressure? How...Ch. 13 - 14. What is the difference between a dilute...Ch. 13 - 15. Define the concentration units mass percent...Ch. 13 - Prob. 16ECh. 13 - 17. How does the presence of a nonvolatile solute...Ch. 13 - What are colligative properties?Ch. 13 - Prob. 19ECh. 13 - Prob. 20ECh. 13 - 21. Two shipwreck survivors were rescued from a...Ch. 13 - 22 Why are intravenous fluids always isoosmotic...Ch. 13 - Prob. 23ECh. 13 - Prob. 24ECh. 13 - Identify the solute and solvent in each solution....Ch. 13 - Prob. 26ECh. 13 - Pick an appropriate solvent from Table 13.2 to...Ch. 13 - Prob. 28ECh. 13 - What are the dissolved particles in a solution...Ch. 13 - What are the dissolved particles in a solution...Ch. 13 - A solution contains 35 g of Nacl per 100 g of...Ch. 13 - 32. A solution contains 28 g of per 100 g of...Ch. 13 - A KNO3 solution containing 45 g of KNO3 per 100 g...Ch. 13 - Prob. 34ECh. 13 - Refer to Figure 13.4 to determine whether each of...Ch. 13 - Prob. 36ECh. 13 - Prob. 37ECh. 13 - Prob. 38ECh. 13 - Scuba divers breathing air at increased pressure...Ch. 13 - Prob. 40ECh. 13 - Prob. 41ECh. 13 - Prob. 42ECh. 13 - 43. A soft drink contains 42 g of sugar in 311 g...Ch. 13 - A soft drink contains 32 mg of sodium in 309 g of...Ch. 13 - Prob. 45ECh. 13 - Prob. 46ECh. 13 - Prob. 47ECh. 13 - Prob. 48ECh. 13 - Prob. 49ECh. 13 - Prob. 50ECh. 13 - Prob. 51ECh. 13 - Prob. 52ECh. 13 - Prob. 53ECh. 13 - A dioxin-contaminated water source contains 0.085%...Ch. 13 - Prob. 55ECh. 13 - Prob. 56ECh. 13 - Prob. 57ECh. 13 - Prob. 58ECh. 13 - Calculate the molarity of each solution. a. 0.127...Ch. 13 - Prob. 60ECh. 13 - Calculate the molarity of each solution. a. 22.6 g...Ch. 13 - Prob. 62ECh. 13 - 63. A 205-mL sample of ocean water contains 6.8 g...Ch. 13 - 64. A 355-mL can of soda pop contains 41 g of...Ch. 13 - Prob. 65ECh. 13 - Prob. 66ECh. 13 - Prob. 67ECh. 13 - Prob. 68ECh. 13 - Prob. 69ECh. 13 - Prob. 70ECh. 13 - Calculate the mass of NaCl in a 35-mL sample of a...Ch. 13 - 72. Calculate the mass of glucose in a 105-mL...Ch. 13 - Prob. 73ECh. 13 - 74. A laboratory procedure calls for making 500.0...Ch. 13 - 75. How many liters of a 0.500 M sucrose solution...Ch. 13 - Prob. 76ECh. 13 - Prob. 77ECh. 13 - Prob. 78ECh. 13 - Prob. 79ECh. 13 - Prob. 80ECh. 13 - Prob. 81ECh. 13 - Prob. 82ECh. 13 - Prob. 83ECh. 13 - 84. Describe how you would make 500.0 mL of a...Ch. 13 - To what volume should you dilute 25 mL of a 12 M...Ch. 13 - Prob. 86ECh. 13 - Prob. 87ECh. 13 - Prob. 88ECh. 13 - 89. Determine the volume of 0.150 M NaOH solution...Ch. 13 - Prob. 90ECh. 13 - Consider the reaction:...Ch. 13 - Prob. 92ECh. 13 - Prob. 93ECh. 13 - 94. A 25.0-mL sample of an unknown solution...Ch. 13 - 95. What is the minimum amount of necessary to...Ch. 13 - Prob. 96ECh. 13 - Prob. 97ECh. 13 - Prob. 98ECh. 13 - Prob. 99ECh. 13 - Prob. 100ECh. 13 - Prob. 101ECh. 13 - Prob. 102ECh. 13 - Prob. 103ECh. 13 - Prob. 104ECh. 13 - A glucose solution contains 55.8 g of glucose...Ch. 13 - 106. An ethylene glycol solution contains 21.2 g...Ch. 13 - Prob. 107ECh. 13 - Prob. 108ECh. 13 - Prob. 109ECh. 13 - Prob. 110ECh. 13 - Prob. 111ECh. 13 - Prob. 112ECh. 13 - What is the molarity of an aqueous solution that...Ch. 13 - Prob. 114ECh. 13 - Consider the reaction:...Ch. 13 - Prob. 116ECh. 13 - Prob. 117ECh. 13 - Prob. 118ECh. 13 - Prob. 119ECh. 13 - Prob. 120ECh. 13 - 121. An ethylene glycol solution is made using...Ch. 13 - A sucrose solution is made using 144 g of sucrose...Ch. 13 - A 250.0-mL sample of a 5.00 M glucose (C6H12O6)...Ch. 13 - Prob. 124ECh. 13 - Prob. 125ECh. 13 - 126. An aqueous solution containing 35.9 g of an...Ch. 13 - Prob. 127ECh. 13 - Prob. 128ECh. 13 - A 125-g sample contains only glucose (C6H12O6) and...Ch. 13 - A 13.03-g sample contains only ethylene glycol...Ch. 13 - Consider the molecular views of osmosis cells. For...Ch. 13 - What is wrong with this molecular view of a sodium...Ch. 13 - Prob. 133ECh. 13 - Prob. 134ECh. 13 - Prob. 135QGWCh. 13 - Prob. 136QGWCh. 13 - Prob. 137QGWCh. 13 - Prob. 138QGWCh. 13 - Data Interpretation and Analysis Read CHEMISTRY IN...
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