INTOR TO CHEMISTRY LLF
5th Edition
ISBN: 9781264501731
Author: BAUER
Publisher: MCG
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Chapter 13, Problem 101QP
Interpretation Introduction
Interpretation:
The change on titrating an acid of
Concept Introduction:
Indicators are brightly coloured organic dyes and are weak acids and bases. They give different colours in different
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Identify and provide an explanation that distinguishes a qualitative and quantitative chemical analysis. Provide examples.
Identify and provide an explanation of the operational principles behind a Atomic Absorption Spectrometer (AAS). List the steps involved.
Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
Chapter 13 Solutions
INTOR TO CHEMISTRY LLF
Ch. 13 - How do acids and bases differ from other...Ch. 13 - Prob. 2QCCh. 13 - Prob. 3QCCh. 13 - Prob. 4QCCh. 13 - Prob. 5QCCh. 13 - Prob. 6QCCh. 13 - Prob. 1PPCh. 13 - Prob. 2PPCh. 13 - Prob. 3PPCh. 13 - Prob. 4PP
Ch. 13 - Prob. 5PPCh. 13 - Prob. 6PPCh. 13 - Prob. 7PPCh. 13 - Prob. 8PPCh. 13 - Prob. 9PPCh. 13 - Prob. 10PPCh. 13 - Prob. 11PPCh. 13 - Prob. 12PPCh. 13 - Prob. 13PPCh. 13 - Prob. 14PPCh. 13 - Prob. 15PPCh. 13 - Prob. 1QPCh. 13 - Prob. 2QPCh. 13 - Prob. 3QPCh. 13 - Prob. 4QPCh. 13 - Prob. 5QPCh. 13 - Prob. 6QPCh. 13 - Prob. 7QPCh. 13 - Prob. 8QPCh. 13 - Prob. 9QPCh. 13 - Prob. 10QPCh. 13 - Prob. 11QPCh. 13 - Prob. 12QPCh. 13 - Prob. 13QPCh. 13 - Prob. 14QPCh. 13 - Prob. 15QPCh. 13 - Prob. 16QPCh. 13 - Prob. 17QPCh. 13 - Prob. 18QPCh. 13 - Prob. 19QPCh. 13 - Prob. 20QPCh. 13 - Prob. 21QPCh. 13 - Prob. 22QPCh. 13 - Prob. 23QPCh. 13 - Prob. 24QPCh. 13 - Prob. 25QPCh. 13 - Prob. 26QPCh. 13 - How do strong acids and bases differ from weak...Ch. 13 - Prob. 28QPCh. 13 - Prob. 29QPCh. 13 - Prob. 30QPCh. 13 - Prob. 31QPCh. 13 - Prob. 32QPCh. 13 - Prob. 33QPCh. 13 - Prob. 34QPCh. 13 - Prob. 35QPCh. 13 - Prob. 36QPCh. 13 - Prob. 37QPCh. 13 - Prob. 38QPCh. 13 - Sodium fluoride, NaF, and sodium acetate,...Ch. 13 - Prob. 40QPCh. 13 - Prob. 41QPCh. 13 - Prob. 42QPCh. 13 - Prob. 43QPCh. 13 - Prob. 44QPCh. 13 - Prob. 45QPCh. 13 - Prob. 46QPCh. 13 - Prob. 47QPCh. 13 - Prob. 48QPCh. 13 - Prob. 49QPCh. 13 - Prob. 50QPCh. 13 - Prob. 51QPCh. 13 - Prob. 52QPCh. 13 - Prob. 53QPCh. 13 - Prob. 54QPCh. 13 - Prob. 55QPCh. 13 - Prob. 56QPCh. 13 - Prob. 57QPCh. 13 - Prob. 58QPCh. 13 - Prob. 59QPCh. 13 - Prob. 60QPCh. 13 - Prob. 61QPCh. 13 - Prob. 62QPCh. 13 - Prob. 63QPCh. 13 - Prob. 64QPCh. 13 - Prob. 65QPCh. 13 - What is the pH range for acidic solutions? For...Ch. 13 - Prob. 67QPCh. 13 - Prob. 68QPCh. 13 - Prob. 69QPCh. 13 - Prob. 70QPCh. 13 - Prob. 71QPCh. 13 - Prob. 72QPCh. 13 - Prob. 73QPCh. 13 - Prob. 74QPCh. 13 - Prob. 75QPCh. 13 - Prob. 76QPCh. 13 - Prob. 77QPCh. 13 - Prob. 78QPCh. 13 - Prob. 79QPCh. 13 - Prob. 80QPCh. 13 - Prob. 81QPCh. 13 - Prob. 82QPCh. 13 - Prob. 83QPCh. 13 - Prob. 84QPCh. 13 - Prob. 85QPCh. 13 - Prob. 86QPCh. 13 - Prob. 87QPCh. 13 - Prob. 88QPCh. 13 - Prob. 89QPCh. 13 - Prob. 90QPCh. 13 - Prob. 91QPCh. 13 - Prob. 92QPCh. 13 - Prob. 93QPCh. 13 - Prob. 94QPCh. 13 - Prob. 95QPCh. 13 - Prob. 96QPCh. 13 - Prob. 97QPCh. 13 - Prob. 98QPCh. 13 - Prob. 99QPCh. 13 - Prob. 100QPCh. 13 - Prob. 101QPCh. 13 - What would you expect to observe if you ran a...Ch. 13 - Prob. 103QPCh. 13 - Prob. 104QPCh. 13 - Prob. 105QPCh. 13 - Prob. 106QPCh. 13 - Prob. 107QPCh. 13 - Prob. 108QPCh. 13 - Prob. 109QPCh. 13 - Prob. 110QPCh. 13 - Prob. 111QPCh. 13 - Prob. 112QPCh. 13 - Prob. 113QPCh. 13 - Prob. 114QPCh. 13 - Prob. 115QPCh. 13 - Prob. 116QPCh. 13 - Prob. 117QPCh. 13 - Prob. 118QPCh. 13 - Prob. 119QPCh. 13 - Prob. 120QPCh. 13 - Prob. 121QPCh. 13 - Prob. 122QPCh. 13 - Prob. 123QPCh. 13 - Prob. 124QPCh. 13 - Prob. 125QPCh. 13 - Prob. 126QPCh. 13 - Prob. 127QPCh. 13 - Prob. 128QPCh. 13 - Prob. 129QPCh. 13 - What is the pH of a mixture that contains...Ch. 13 - Prob. 131QPCh. 13 - Prob. 132QPCh. 13 - Prob. 133QPCh. 13 - Which of the following weak acids has the anion...Ch. 13 - Prob. 135QPCh. 13 - Prob. 136QPCh. 13 - Prob. 137QPCh. 13 - Prob. 138QPCh. 13 - Prob. 139QPCh. 13 - Prob. 140QPCh. 13 - Prob. 141QPCh. 13 - Prob. 142QPCh. 13 - Prob. 143QPCh. 13 - Prob. 144QPCh. 13 - Prob. 145QPCh. 13 - Prob. 146QPCh. 13 - When 10.0mLofa0.10MHCl solution is diluted to...Ch. 13 - Consider a buffer solution prepared by adding...
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Introduction to Titrimetric analysis; Author: Vidya-mitra;https://www.youtube.com/watch?v=uykGVfn9q24;License: Standard Youtube License