(a) Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified. Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Question

What are the IUPAC Names of all the compounds in the picture?

Answer 1

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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What are the IUPAC Names of all the compounds in the picture?

1) a) Give the dominant Intermolecular Force (IMF) in a sample of each of the following compounds. Please show your work. (8) SF2, CH,OH, C₂H₂ b) Based on your answers given above, list the compounds in order of their Boiling Point from low to high. (8)

19.78 Write the products of the following sequences of reactions. Refer to your reaction road- maps to see how the combined reactions allow you to "navigate" between the different functional groups. Note that you will need your old Chapters 6-11 and Chapters 15-18 roadmaps along with your new Chapter 19 roadmap for these. (a) 1. BHS 2. H₂O₂ 3. H₂CrO4 4. SOCI₂ (b) 1. Cl₂/hv 2. KOLBU 3. H₂O, catalytic H₂SO4 4. H₂CrO4 Reaction Roadmap An alkene 5. EtOH 6.0.5 Equiv. NaOEt/EtOH 7. Mild H₂O An alkane 1.0 2. (CH3)₂S 3. H₂CrO (d) (c) 4. Excess EtOH, catalytic H₂SO OH 4. Mild H₂O* 5.0.5 Equiv. NaOEt/EtOH An alkene 6. Mild H₂O* A carboxylic acid 7. Mild H₂O* 1. SOC₁₂ 2. EtOH 3.0.5 Equiv. NaOEt/E:OH 5.1.0 Equiv. NaOEt 6. NH₂ (e) 1. 0.5 Equiv. NaOEt/EtOH 2. Mild H₂O* Br (f) i H An aldehyde 1. Catalytic NaOE/EtOH 2. H₂O*, heat 3. (CH,CH₂)₂Culi 4. Mild H₂O* 5.1.0 Equiv. LDA Br An ester 4. NaOH, H₂O 5. Mild H₂O* 6. Heat 7. MgBr 8. Mild H₂O* 7. Mild H₂O+

Answer 2

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 3

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 4

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 5

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 6

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 7

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 8

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 9

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 10

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 11

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 12

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Ch. 12C.1 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 12C.1 - Prob. 2P Ch. 12C.2 - How many 1H NMR signals does each...Ch. 12C.2 - How many 1H NMR signals does each compound give?...Ch. 12C.2 - Label the protons in each highlighted CH2 group as...Ch. 12C.2 - How many 1H NMR signals would you expect for each...Ch. 12C.3 - Prob. 9P Ch. 12C.3 - For each compound, first label each different type...Ch. 12C.3 - Label each statement as True or False. a. When a...Ch. 12C.4 - Prob. 12P

Solution Summary: The author explains that the protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

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