(a) Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified. Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Question

5) Calculate the flux of oxygen between the ocean and the atmosphere(2 pts), given that: (from Box 5.1, pg. 88 of your text): Temp = 18°C Salinity = 35 ppt Density = 1025 kg/m3 Oxygen concentration measured in bulk water = 263.84 mmol/m3 Wind speed = 7.4 m/s Oxygen is observed to be about 10% initially supersaturated What is flux if the temperature is 10°C ? (2 pts) (Hint: use the same density in your calculations). Why do your calculated values make sense (or not) based on what you know about the relationship between gas solubility and temperature (1 pt)?

Answer 1

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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5) Calculate the flux of oxygen between the ocean and the atmosphere(2 pts), given that: (from Box 5.1, pg. 88 of your text): Temp = 18°C Salinity = 35 ppt Density = 1025 kg/m3 Oxygen concentration measured in bulk water = 263.84 mmol/m3 Wind speed = 7.4 m/s Oxygen is observed to be about 10% initially supersaturated What is flux if the temperature is 10°C ? (2 pts) (Hint: use the same density in your calculations). Why do your calculated values make sense (or not) based on what you know about the relationship between gas solubility and temperature (1 pt)?

Find a molecular formula for these unknowns

(ME EX2) Prblms 8-11 Can you please explain problems 8 -11 to me in detail, step by step? Thank you so much! If needed color code them for me.

Answer 2

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 3

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 4

Question

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

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Answer 5

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 6

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 7

Chapter 12C.3, Problem 9P

Interpretation Introduction

(a)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 8

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 9

Interpretation Introduction

(b)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 10

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 11

Interpretation Introduction

(c)

Interpretation: The protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

Concept introduction: Depending upon the electron density or the concentration of electron around the proton the chemical shift values of the proton varies relative to the reference signal. The terms, upfield and downfield expresses the relative location of signals. The meaning of upfield is to the right and of downfield is to the left.

Answer 12

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Ch. 12C.1 - Problem 14.1 The NMR spectrum of recorded on a ...Ch. 12C.1 - Prob. 2P Ch. 12C.2 - How many 1H NMR signals does each...Ch. 12C.2 - How many 1H NMR signals does each compound give?...Ch. 12C.2 - Label the protons in each highlighted CH2 group as...Ch. 12C.2 - How many 1H NMR signals would you expect for each...Ch. 12C.3 - Prob. 9P Ch. 12C.3 - For each compound, first label each different type...Ch. 12C.3 - Label each statement as True or False. a. When a...Ch. 12C.4 - Prob. 12P

Solution Summary: The author explains that the protons on the highlighted carbons of the given compound that absorbs farther downfield are to be identified.

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Chapter 12C Solutions