ORGANIC CHEMISTRY-ACCESS
ORGANIC CHEMISTRY-ACCESS
6th Edition
ISBN: 9781260475586
Author: SMITH
Publisher: MCG
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Chapter 12C, Problem 70P

Propose a structure consistent with each set of data.

a. Compound J: molecular ion at 72 ; IR peak at 1710 cm 1 ; 1 H NMR data (ppm) at 1 .0 ( triplet 3 H ) , 2 .1 ( singlet, 3 H ) , and 2.4 ( quartet, 2 H )

b. Compound K: molecular ion at 88 ; IR peak at 3600 3200 cm 1 ; 1 H NMR data (ppm) at 0 .9 ( triplet 3 H ) , 1 .2 ( singlet, 6 H ) , 1.5 ( quartet, 2 H ) , and 1.6 ( singlet, 1 H ) .9 (triplet, 3 H), 1.2 (singlet, 6 H)

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