ORGANIC CHEMISTRY II LAB MANUAL>CUSTOM<
9th Edition
ISBN: 9780534261641
Author: SIMEK
Publisher: Cengage Learning
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Chapter 12.9A, Problem 12.4P
Spectra are given for three compounds. Each compound has one or more of the following functional groups alcohol:
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Topic: Photochemistry and Photophysics of Supramolecules
Chapter 12 Solutions
ORGANIC CHEMISTRY II LAB MANUAL>CUSTOM<
Ch. 12.3 - Complete the following conversion table. (cm1)...Ch. 12.5 - Which of the bonds shown in red are expected to...Ch. 12.7C - For each hydrocarbon spectrum, determine whether...Ch. 12.9A - Spectra are given for three compounds. Each...Ch. 12.10 - The infrared spectra for three compounds are...Ch. 12.12 - Prob. 12.6PCh. 12.14B - Identify which of these four mass spectra indicate...Ch. 12.15A - Show the fragmentation that accounts for the...Ch. 12.15A - Show the fragmentations that give rise to the...Ch. 12.15B - Ethers are not easily differentiated by their...
Ch. 12.15C - Prob. 12.11PCh. 12 - Prob. 12.12SPCh. 12 - Prob. 12.13SPCh. 12 - All of the following compounds absorb infrared...Ch. 12 - Prob. 12.15SPCh. 12 - Four infrared spectra are shown, corresponding to...Ch. 12 - Predict the masses and the structures of the most...Ch. 12 - Prob. 12.18SPCh. 12 - Prob. 12.19SPCh. 12 - (A true story) While organizing the undergraduate...Ch. 12 - Prob. 12.21SPCh. 12 - Prob. 12.22SPCh. 12 - An unknown, foul-smelling hydrocarbon gives the...Ch. 12 - covered a synthesis of alkynes by a double...Ch. 12 - Three IR spectra are shown, corresponding to three...Ch. 12 - Prob. 12.26SPCh. 12 - Prob. 12.27SPCh. 12 - Prob. 12.28SPCh. 12 - The ultimate test of fluency in MS and IR is...Ch. 12 - Prob. 12.30SPCh. 12 - Consider the following four structures, followed...
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- When two solutions, one of 0.1 M KCl (I) and the other of 0.1 M MCl (II), are brought into contact by a membrane. The cation M cannot cross the membrane. At equilibrium, x moles of K+ will have passed from solution (I) to (II). To maintain the neutrality of the two solutions, x moles of Cl- will also have to pass from I to II. Explain this equality: (0.1 - x)/x = (0.1 + x)/(0.1 - x)arrow_forwardCalculate the variation in the potential of the Pt/MnO4-, Mn2+ pair with pH, indicating the value of the standard potential. Data: E0 = 1.12.arrow_forwardGiven the cell: Pt l H2(g) l dis X:KCl (sat) l Hg2Cl2(s) l Hg l Pt. Calculate the emf of the cell as a function of pH.arrow_forward
- The decimolar calomel electrode has a potential of 0.3335 V at 25°C compared to the standard hydrogen electrode. If the standard reduction potential of Hg22+ is 0.7973 V and the solubility product of Hg2Cl2 is 1.2x 10-18, find the activity of the chlorine ion at this electrode.Data: R = 8.314 J K-1 mol-1, F = 96485 C mol-1, T = 298.15 K.arrow_forward2. Add the following group of numbers using the correct number of significant figures for the answer. Show work to earn full credit such as rounding off the answer to the correct number of significant figures. Replace the question marks with the calculated answers or write the calculated answers near the question marks. 10916.345 37.40832 5.4043 3.94 + 0.0426 ? (7 significant figures)arrow_forwardThe emf at 25°C of the cell: Pt l H2(g) l dis X:KCl (sat) l Hg2Cl2(s) l Hg l Pt was 612 mV. When solution X was replaced by normal phosphate buffer solution with a pH of 6.86, the emf was 741 mV. Calculate the pH of solution X.arrow_forward
- Indicate how to calculate the potential E of the reaction Hg2Cl2(s) + 2e ⇄ 2Hg + 2Cl- as a function of the concentration of Cl- ions. Data: the solubility product of Hg2Cl2.arrow_forwardHow can Beer’s Law be used to determine the concentration in a selected food sample. Provide an in-depth discussion and examples of this.arrow_forwardb) H3C- H3C Me CH 3 I HN Me H+arrow_forward
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