General Chemistry
General Chemistry
7th Edition
ISBN: 9780073402758
Author: Chang, Raymond/ Goldsby
Publisher: McGraw-Hill College
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Chapter 12.7, Problem 1RC
Interpretation Introduction

Interpretation:

Among the given phase diagrams, the one which corresponds to sublimation at 1 atm without melting, has to be identified.

Concept Introduction:

Phase diagram: In any phase diagram, the thick lines indicate the equilibrium existing between two phases. In the given phase diagrams, the very 1st phase from the top is the solid phase and the next adjacent phase is the liquid phase. The phase below the liquid phase is the gaseous phase which will be the bottom portion of the entire phase diagram.

Melting is the process in which the solid phase and the liquid phase exists in equilibrium. It means the solid phase changes into the liquid phase.

Sublimation is the process in which the solid phase and the vapor phase exists in equilibrium. It means the solid phase changes into vapor phase directly without changing into the intermediate liquid phase.

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1. Answer the questions about the following reaction: (a) Draw in the arrows that can be used make this reaction occur and draw in the product of substitution in this reaction. Be sure to include any relevant stereochemistry in the product structure. + SK F Br + (b) In which solvent would this reaction proceed the fastest (Circle one) Methanol Acetone (c) Imagine that you are working for a chemical company and it was your job to perform a similar reaction to the one above, with the exception of the S atom in this reaction being replaced by an O atom. During the reaction, you observe the formation of three separate molecules instead of the single molecule obtained above. What is the likeliest other products that are formed? Draw them in the box provided.
3. For the reactions below, draw the arrows corresponding to the transformations and draw in the boxes the reactants or products as indicated. Note: Part A should have arrows drawn going from the reactants to the middle structure and the arrows on the middle structure that would yield the final structure. For part B, you will need to draw in the reactant before being able to draw the arrows corresponding to product formation. A. B. Rearrangement ΘΗ
2. Draw the arrows required to make the following reactions occur. Please ensure your arrows point from exactly where you want to exactly where you want. If it is unclear from where arrows start or where they end, only partial credit will be given. Note: You may need to draw in lone pairs before drawing the arrows. A. B. H-Br 人 C Θ CI H Cl Θ + Br O

Chapter 12 Solutions

General Chemistry

Ch. 12.7 - Prob. 1RCCh. 12 - Prob. 12.1QPCh. 12 - Prob. 12.2QPCh. 12 - Prob. 12.3QPCh. 12 - Prob. 12.4QPCh. 12 - Prob. 12.5QPCh. 12 - Prob. 12.6QPCh. 12 - Prob. 12.7QPCh. 12 - Prob. 12.8QPCh. 12 - Prob. 12.9QPCh. 12 - Prob. 12.10QPCh. 12 - Prob. 12.11QPCh. 12 - Prob. 12.12QPCh. 12 - Prob. 12.13QPCh. 12 - 12.14 Diethyl ether has a boiling point of 34.5°C,...Ch. 12 - Prob. 12.15QPCh. 12 - Prob. 12.16QPCh. 12 - Prob. 12.17QPCh. 12 - 12.18 What kind of attractive forces must be...Ch. 12 - Prob. 12.19QPCh. 12 - Prob. 12.20QPCh. 12 - Prob. 12.21QPCh. 12 - Prob. 12.22QPCh. 12 - Prob. 12.23QPCh. 12 - Prob. 12.24QPCh. 12 - Prob. 12.25QPCh. 12 - Prob. 12.26QPCh. 12 - Prob. 12.27QPCh. 12 - Prob. 12.28QPCh. 12 - Prob. 12.29QPCh. 12 - Prob. 12.30QPCh. 12 - Prob. 12.31QPCh. 12 - Prob. 12.32QPCh. 12 - Prob. 12.33QPCh. 12 - Prob. 12.34QPCh. 12 - Prob. 12.35QPCh. 12 - 12.36 A solid is hard, brittle, and electrically...Ch. 12 - Prob. 12.37QPCh. 12 - Prob. 12.38QPCh. 12 - Prob. 12.39QPCh. 12 - Prob. 12.40QPCh. 12 - Prob. 12.41QPCh. 12 - Prob. 12.42QPCh. 12 - Prob. 12.43QPCh. 12 - Prob. 12.44QPCh. 12 - Prob. 12.45QPCh. 12 - Prob. 12.46QPCh. 12 - Prob. 12.47QPCh. 12 - Prob. 12.48QPCh. 12 - Prob. 12.49QPCh. 12 - Prob. 12.50QPCh. 12 - Prob. 12.51QPCh. 12 - Prob. 12.52QPCh. 12 - Prob. 12.53QPCh. 12 - Prob. 12.54QPCh. 12 - Prob. 12.55QPCh. 12 - Prob. 12.56QPCh. 12 - Prob. 12.57QPCh. 12 - Prob. 12.58QPCh. 12 - Prob. 12.59QPCh. 12 - Prob. 12.60QPCh. 12 - Prob. 12.61QPCh. 12 - Prob. 12.62QPCh. 12 - 12.63 What is the relationship between...Ch. 12 - Prob. 12.64QPCh. 12 - 12.65 Why is solid carbon dioxide called dry ice? Ch. 12 - Prob. 12.66QPCh. 12 - 12.67 Referring to Figure 12.28, estimate the...Ch. 12 - Prob. 12.68QPCh. 12 - Prob. 12.69QPCh. 12 - Prob. 12.70QPCh. 12 - Prob. 12.71QPCh. 12 - Prob. 12.72QPCh. 12 - Prob. 12.73QPCh. 12 - Prob. 12.74QPCh. 12 - 12.75 These compounds are liquid at −10°C; their...Ch. 12 - 12.76 Freeze-dried coffee is prepared by freezing...Ch. 12 - Prob. 12.77QPCh. 12 - 12.78 Steam at 100°C causes more serious burns...Ch. 12 - 12.79 Vapor pressure measurements at several...Ch. 12 - Prob. 12.80QPCh. 12 - Prob. 12.81QPCh. 12 - Prob. 12.82QPCh. 12 - Prob. 12.83QPCh. 12 - Prob. 12.84QPCh. 12 - Prob. 12.85QPCh. 12 - Prob. 12.86QPCh. 12 - Prob. 12.87QPCh. 12 - Prob. 12.88QPCh. 12 - Prob. 12.89QPCh. 12 - 12.90 Name the kinds of attractive forces that...Ch. 12 - Prob. 12.91QPCh. 12 - Prob. 12.92QPCh. 12 - Prob. 12.93QPCh. 12 - Prob. 12.94QPCh. 12 - Prob. 12.95QPCh. 12 - Prob. 12.96QPCh. 12 - Prob. 12.97QPCh. 12 - Prob. 12.98QPCh. 12 - 12.99 The liquid-vapor boundary line in the phase...Ch. 12 - Prob. 12.100QPCh. 12 - Prob. 12.101QPCh. 12 - Prob. 12.102QPCh. 12 - Prob. 12.103QPCh. 12 - Prob. 12.104QPCh. 12 - Prob. 12.105QPCh. 12 - Prob. 12.106QPCh. 12 - 12.107 The following graph shows approximate plots...Ch. 12 - Prob. 12.108QPCh. 12 - Prob. 12.109QPCh. 12 - Prob. 12.110QPCh. 12 - Prob. 12.111QPCh. 12 - Prob. 12.112QPCh. 12 - Prob. 12.113QPCh. 12 - Prob. 12.114QPCh. 12 - 12.115 Use the concept of intermolecular forces to...Ch. 12 - Prob. 12.116QPCh. 12 - 12.117 What is the origin of dark spots on the...Ch. 12 - Prob. 12.118QPCh. 12 - 12.119 The electrical conductance of copper metal...Ch. 12 - Prob. 12.120SPCh. 12 - Prob. 12.121SPCh. 12 - Prob. 12.122SPCh. 12 - Prob. 12.123SPCh. 12 - Prob. 12.124SPCh. 12 - 12.125 The boiling point of methanol is 65.0°C and...Ch. 12 - Prob. 12.126SPCh. 12 - Prob. 12.127SPCh. 12 - Prob. 12.128SPCh. 12 - Prob. 12.129SP
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