EBK THERMODYNAMICS: AN ENGINEERING APPR
8th Edition
ISBN: 8220100257056
Author: CENGEL
Publisher: YUZU
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Chapter 12.6, Problem 62P
To determine
To demonstrate the Joule-Thomson coefficient is given by
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One mole of a gas is expanded isothermally at 300 Kelvins from 5.00 MegaPascal to 0.10 MegaPascal. If this gas obeys the equation of state given below and from this B is equal to 2.0 x10^4 L/(mol-K^2), answer the question that follow.
Calculate the change in molar Gibbs free energy (in KJ/mole) for this process. Express answer in THREE SIGNIFICANT FIGURES.
Q4 Show that for a gas obeying van der Walls equation of state,
2a
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Derive an expression for the specific heat difference of a substance whose equation of state is:
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Chapter 12 Solutions
EBK THERMODYNAMICS: AN ENGINEERING APPR
Ch. 12.6 - What is the difference between partial...Ch. 12.6 - Consider a function z(x, y) and its partial...Ch. 12.6 - Prob. 3PCh. 12.6 - Conside the function z(x, y), its partial...Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - Consider air at 350 K and 0.75 m3/kg. Using Eq....Ch. 12.6 - 12–7 Nitrogen gas at 400 K and 300 kPa behaves as...Ch. 12.6 - Nitrogen gas at 800 R and 50 psia behaves as an...Ch. 12.6 - Prob. 9PCh. 12.6 - Using the equation of state P(v a) = RT, verify...
Ch. 12.6 - Prob. 11PCh. 12.6 - Verify the validity of the last Maxwell relation...Ch. 12.6 - Prob. 14PCh. 12.6 - Prob. 15PCh. 12.6 - Prob. 16PCh. 12.6 - Prob. 17PCh. 12.6 - Prove that (PT)=kk1(PT)v.Ch. 12.6 - Prob. 19PCh. 12.6 - Prob. 20PCh. 12.6 - Using the Clapeyron equation, estimate the...Ch. 12.6 - Prob. 22PCh. 12.6 - Prob. 23PCh. 12.6 - Determine the hfg of refrigerant-134a at 10F on...Ch. 12.6 - Prob. 25PCh. 12.6 - Prob. 26PCh. 12.6 - Prob. 27PCh. 12.6 - Prob. 28PCh. 12.6 - Prob. 29PCh. 12.6 - 12–30 Show that =
Ch. 12.6 - Prob. 31PCh. 12.6 - Prob. 32PCh. 12.6 - Prob. 33PCh. 12.6 - Prob. 34PCh. 12.6 - Prob. 35PCh. 12.6 - Prob. 36PCh. 12.6 - Determine the change in the internal energy of...Ch. 12.6 - Prob. 38PCh. 12.6 - Determine the change in the entropy of helium, in...Ch. 12.6 - Prob. 40PCh. 12.6 - Derive expressions for (a) u, (b) h, and (c) s for...Ch. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Show that cpcv=T(PT)V(VT)P.Ch. 12.6 - Prob. 44PCh. 12.6 - Prob. 45PCh. 12.6 - Derive an expression for the specific heat...Ch. 12.6 - Derive an expression for the isothermal...Ch. 12.6 - Show that = ( P/ T)v.Ch. 12.6 - Prob. 49PCh. 12.6 - Prob. 50PCh. 12.6 - Show that the enthalpy of an ideal gas is a...Ch. 12.6 - Prob. 52PCh. 12.6 - Prob. 53PCh. 12.6 - The pressure of a fluid always decreases during an...Ch. 12.6 - Does the Joule-Thomson coefficient of a substance...Ch. 12.6 - Will the temperature of helium change if it is...Ch. 12.6 - Prob. 59PCh. 12.6 - Prob. 60PCh. 12.6 - 12–61E Estimate the Joule-Thomson-coefficient of...Ch. 12.6 - Prob. 62PCh. 12.6 - Consider a gas whose equation of state is P(v a)...Ch. 12.6 - Prob. 64PCh. 12.6 - On the generalized enthalpy departure chart, the...Ch. 12.6 - Why is the generalized enthalpy departure chart...Ch. 12.6 - Prob. 67PCh. 12.6 - Prob. 68PCh. 12.6 - Prob. 69PCh. 12.6 - Prob. 70PCh. 12.6 - Prob. 71PCh. 12.6 - Prob. 72PCh. 12.6 - Prob. 73PCh. 12.6 - Prob. 75PCh. 12.6 - Propane is compressed isothermally by a...Ch. 12.6 - Prob. 78PCh. 12.6 - Prob. 80RPCh. 12.6 - Starting with the relation dh = T ds + vdP, show...Ch. 12.6 - Show that cv=T(vT)s(PT)vandcp=T(PT)s(vT)PCh. 12.6 - Temperature and pressure may be defined as...Ch. 12.6 - For ideal gases, the development of the...Ch. 12.6 - Prob. 85RPCh. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - For a homogeneous (single-phase) simple pure...Ch. 12.6 - Prob. 88RPCh. 12.6 - Estimate the cpof nitrogen at 300 kPa and 400 K,...Ch. 12.6 - Prob. 90RPCh. 12.6 - Prob. 91RPCh. 12.6 - An adiabatic 0.2-m3 storage tank that is initially...Ch. 12.6 - Prob. 93RPCh. 12.6 - Methane is to be adiabatically and reversibly...Ch. 12.6 - Prob. 96RPCh. 12.6 - Prob. 98RPCh. 12.6 - Prob. 99RPCh. 12.6 - Prob. 100FEPCh. 12.6 - Consider the liquidvapor saturation curve of a...Ch. 12.6 - Prob. 102FEPCh. 12.6 - For a gas whose equation of state is P(v b) = RT,...
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- At low pressures, the compressibility factor of a van der Waals gas is given by the equation: Z = PV/RT = 1+(b- a/RT) P/RT Calculate the fugacity of nitrogen gas at 3000 K and 0.05 bar. The van der Waals constants of nitrogen gas are a = 1.408 L^2-bar-mol^2 and b = 0.03913 L-mol^-1. By investigating the fugacity coefficient, what can be said about nitrogen at this temperature and pressure? *final answer in 4 decimalsarrow_forwardYou have a 3.00-liter container filled with N₂ at 25°C and 4.25 atm pressure connected to a 2.00-liter container filled with Ar at 25°C and 2.75 atm pressure. A stopcock connecting the containers is opened and the gases are allowed to equilibrate between the two containers. What is the final pressure (in atm) in the two containers if the temperature remains at 25°C? Assume ideal behavior.arrow_forwardQ3: In a closed vessel with a volume of 50 dm3 there are 2 moles of an ideal monoatomic gas with cv, m = 12.471 J K-1 mol-1 at 25°C. The vessel was heated to 125°C. Calculate the values of Q, W, AU, AH in Joules and the initial and final pressure in the system. R = 8,314 J K-1 mol-1. Cp,m = 20,785 J K-1 mol-1arrow_forward
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