An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given. Concept Introduction: A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary. IUPAC rules for naming alcohols: Alcohols are named by identifying the parent compound and replacing the –e ending with –ol . Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix. Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group. Name and number all substituent, and put them as prefixes to “ alkanol ” name also give the first preference as per the alphabetical order. If an alcohol contains two hydroxyl groups then name it as diol , an alcohol; contains three hydroxyl groups then name it as triol . Common names for alcohols are derived from alkyl group corresponding to the parent compound.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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MISSED THIS? Read Section 19.9 (Pages 878-881); Watch IWE 19.10 Consider the following reaction: CH3OH(g) CO(g) + 2H2(g) (Note that AG,CH3OH(g) = -162.3 kJ/mol and AG,co(g)=-137.2 kJ/mol.) Part A Calculate AG for this reaction at 25 °C under the following conditions: PCH₂OH Pco PH2 0.815 atm = 0.140 atm 0.170 atm Express your answer in kilojoules to three significant figures. Ο ΑΣΦ AG = -150 Submit Previous Answers Request Answer □? kJ × Incorrect; Try Again; 2 attempts remaining Calculate the free energy change under nonstandard conditions (AGrxn) by using the following relationship: AGrxn = AGrxn + RTInQ, AGxn+RTInQ, where AGxn is the standard free energy change, R is the ideal gas constant, T is the temperature in kelvins, a is the reaction quotient. Provide Feedback Next >

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Answer 5

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Answer 6

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

Answer 7

Chapter 12.4, Problem 12.7Q

(a)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

A common nomenclature of naming organic compounds has been developed by IUPAC. By usage of this nomenclature or rules, memorizing of names of organic compounds is not necessary.

IUPAC rules for naming alcohols:

Alcohols are named by identifying the parent compound and replacing the –e ending with –ol.

Ketones are named by identifying the parent compound and replacing the –e ending with –one as suffix.

Lowest possible number should be given for the hydroxyl group present in the parent chain, similarly do for carbonyl group.

Name and number all substituent, and put them as prefixes to “alkanol” name also give the first preference as per the alphabetical order.

If an alcohol contains two hydroxyl groups then name it as diol, an alcohol; contains three hydroxyl groups then name it as triol.

Common names for alcohols are derived from alkyl group corresponding to the parent compound.

Answer 8

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Answer 9

(b)

Interpretation Introduction

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 12.1PP Ch. 12.2 - Prob. 12.2PP Ch. 12.2 - Prob. 12.3PP Ch. 12.2 - Prob. 12.1Q Ch. 12.2 - Prob. 12.2Q Ch. 12.4 - Write an equation representing the reduction of...Ch. 12.4 - Write an equation representing the reduction of...Ch. 12.4 - Prob. 12.6PP Ch. 12.4 - Prob. 12.7PP Ch. 12.4 - Prob. 12.8PP

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Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).

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Chapter 12 Solutions

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Interpretation: An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given. Concept Introduction: Refer part (a).

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Chapter 12 Solutions

Interpretation:

An alcohol reactant involved in Practice Problem 12.8 as primary, secondary, or tertiary alcohol has to be classified and common name and IUPAC name for reactant and product has to be given.

Concept Introduction:

Refer part (a).