The reagent for the given transformation should be identified. Concept introduction: 9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene . Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols. The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis . The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol. Anti-Markovnikov’s rule : unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides. Markovnikov addition : unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Question

Want to see the full answer?

Answer 1

Question

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Students have asked these similar questions

Draw the Lewis structure of C2H4O

a) 5. Circle all acidic (and anticoplanar to the Leaving group) protons in the following molecules, Solve these elimination reactions, and identify the major and minor products where appropriate: 20 points + NaOCH3 Br (2 product

None

Answer 2

Question

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 3

Question

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 4

Question

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Expert Solution & Answer

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 5

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 6

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 7

Chapter 12.3, Problem 8CC

(a)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The reagent for the given transformation should be identified.

Concept introduction:

9-BBN (9-Borabicyclo[3.3.1]nonane) or diborane is used for the hydroboration of alkene. Boron addition to the double bond and subsequent oxidation of the new formed borane yields anti-Markovnikov alcohols.

The role of dilute sulfuric acid is used for the hydration of alkene in organic synthesis.

The oxymercuration reaction is an electrophilic addition reaction, an alkene undergoes oxymercuration and forms neutral alcohol.

Anti-Markovnikov’s rule: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the less substitution position of carbon-carbon double bond which provides alkyl halides.

Markovnikov addition: unsymmetrical alkene reacts with hydrogen halide, halide ions (negative part) goes to the more substitution position of carbon-carbon double bond which provides alkyl halides.

Answer 12

Expert Solution & Answer

Answer 13

Expert Solution & Answer

Answer 14

Want to see the full answer?

Check out a sample textbook solution

See solution

Answer 15

Ch. 12.1 - Prob. 1LTS Ch. 12.1 - PRACTICE the skill Provide an IUPAC name for each...Ch. 12.1 - Safer alternatives to existing insecticides and...Ch. 12.1 - Prob. 3CC Ch. 12.2 - Prob. 4CC Ch. 12.2 - Prob. 2LTS Ch. 12.2 - Prob. 5PTS Ch. 12.2 - Flavonoids are a class of naturally occurring...Ch. 12.3 - Prob. 7CC Ch. 12.3 - Prob. 8CC

Want to see the full answer?

Chapter 12 Solutions