Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 12.3, Problem 12.2P

(a)

Interpretation Introduction

Interpretation:

Without doing the calculations, which given pair occurs at the higher frequency has to be given.

Concept Introduction:

The groups with more force constant and atomic weight will be with high frequency.

(b)

Interpretation Introduction

Interpretation:

Without doing the calculations, which given pair occurs at the higher frequency has to be given.

Concept Introduction:

The groups with more force constant and atomic weight will be with high frequency.

(c)

Interpretation Introduction

Interpretation:

Without doing the calculations, which given pair occurs at the higher frequency has to be given.

Concept Introduction:

The groups with more force constant and atomic weight will be with high frequency.

(d)

Interpretation Introduction

Interpretation:

Without doing the calculations, which given pair occurs at the higher frequency has to be given.

Concept Introduction:

The groups with more force constant and atomic weight will be with high frequency.

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Without doing the calculation, which member of each pair do you expect to occur at the higher frequency? (a) C=O or (b) (c) C=C stretching C=O C=C C=O or C-O stretching C=O -0 C=C or C-O stretching O O C=C C=O (d) C-H or C-C1 stretching C-H C-CI
5. What are the spin system of the following compounds: (a) Cl₂CHCH2CHC₁₂ (b) CF3C=C-H (c) CI- H H H H -Br (d) H3C H CH3
or each of the following molecules, construct the MOS from the 2p, atomic orbitals perpendicular to the plane of the carbon atoms. (a) Cyclobutadiene HC=CH НС—СН HC=CH НС —СH (b) Allyl radical H H H H C=C •C-C, H C-H H C-H H H Indicate which, if any, of these orbitals have identical ener- gies from symmetry considerations. Show the number of electrons occupying each w MO in the ground state, and indicate whether either or both of the molecules are para- magnetic. Assume that the C atoms in the allyl radical are all sp? hybridized. Activate io to S
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