Laboratory Experiments for Chemistry: The Central Science (13th Edition)
13th Edition
ISBN: 9780321949912
Author: Theodore E. Brown, John H. Nelson, Kenneth C. Kemp
Publisher: PEARSON
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Question
Chapter 12, Problem 91E
Interpretation Introduction
Interpretation:
The reason for the “bands” for not being accurate description of bonding in a solid when the solid has nanoscale dimensions is to be determined.
Concept introduction: The number of energy band of the molecular orbital produced from the atomic orbital of nanoscale molecule is less
To determine: The reason for the “bands” for not being accurate description of bonding in a solid when the solid has nanoscale dimensions.
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The table includes macrostates characterized by 4 energy levels (&) that are
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a) Calculate the energy of all the macrostates (in joules). See if they all have
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b) Calculate the macrostate that is most likely to exist. For this macrostate,
show that the population of the levels is consistent with the Boltzmann
distribution.
macrostate 1 macrostate 2 macrostate 3
ε/k (K) Populations
Populations
Populations
300
5
3
4
200
7
9
8
100
15
17
16
0
33
31
32
DATO: k = 1,38×10-23 J K-1
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In an experiment, the viscosity of water was measured at different
temperatures and the table was constructed from the data obtained.
a) Calculate the activation energy of viscous flow (kJ/mol).
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T/°C
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η/cpoise 1,972 1,005 0,656 0,469 0,356
Chapter 12 Solutions
Laboratory Experiments for Chemistry: The Central Science (13th Edition)
Ch. 12.3 - The following diagram shows the combination...Ch. 12.3 -
3.3 The following diagram represents the...Ch. 12.5 -
3.4 The following diagram represents the...Ch. 12.5 - Glycine, an amino acid used by organisms to make...Ch. 12.7 - The following diagram represents a...Ch. 12.7 -
3.7 Nitrogen (N2) and hydrogen (H2) react to form...Ch. 12.7 -
3.8 Nitrogen monoxide and oxygen react to form...Ch. 12.7 - Write "true" or "false" for each statement. a. We...Ch. 12 - Determine the empirical and molecular formulas of...Ch. 12 - a. Combustion analysis of toluene, a common...
Ch. 12 -
3.67 Automotive air bags infilate when sodium...Ch. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 -
12.5 Which of these molecular fragments would...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Prob. 10ECh. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - 12.13 Indicate the type of solid (molecular,...Ch. 12 - Prob. 14ECh. 12 -
12.15 A white substance melts with some...Ch. 12 -
12.16 You are given a white substance that...Ch. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Prob. 22ECh. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 -
12.49 Which would you expect to be the more...Ch. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Clausthalite is a mineral composed of lead...Ch. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - Prob. 71ECh. 12 - Prob. 72ECh. 12 - Prob. 73ECh. 12 - Prob. 74ECh. 12 - Prob. 75ECh. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - Prob. 79ECh. 12 - Prob. 80ECh. 12 - Prob. 81ECh. 12 - Prob. 82ECh. 12 - Prob. 83ECh. 12 - Prob. 84ECh. 12 - Prob. 85ECh. 12 - Prob. 86ECh. 12 - Prob. 87ECh. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Prob. 97ECh. 12 - Prob. 98ECh. 12 - Prob. 99AECh. 12 - Prob. 100AECh. 12 - Prob. 101AECh. 12 - Prob. 102AECh. 12 - Prob. 103AECh. 12 - What type of lattice—primitive cubic body-centered...Ch. 12 - Prob. 105AECh. 12 - Prob. 106AECh. 12 - Prob. 107AECh. 12 - Prob. 108AECh. 12 - Prob. 109AECh. 12 - Prob. 110AECh. 12 - Prob. 111AECh. 12 - Prob. 112AECh. 12 - Prob. 113AECh. 12 - 12.114 Germanium has the same structure as...Ch. 12 - Prob. 115AECh. 12 - Prob. 116AECh. 12 - The karat scale used to describe gold alloys is...Ch. 12 - Prob. 118IECh. 12 - Prob. 119IECh. 12 - Prob. 120IECh. 12 - Prob. 121IECh. 12 - Prob. 122IECh. 12 - Prob. 123IECh. 12 - Prob. 124IECh. 12 - Prob. 125IE
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