Interpretation Introduction To determine: The freezing point and the boiling point of the solution. Explanation Given: Mass of naphthalene ( m n ) is 10 g . Volume of benzene ( V ) is 100 mL . Density of benzene ( ρ ) is 0 .877 g / c m 3 = 0 .877 g / mL . Explanation: Boiling point of benzene ( T pure ) is 80.1 ∘ C . Freezing point of benzene ( T pure ) is 5.5 ∘ C . Molar mass of naphthalene ( MM n ) is 128.171 g / mol . The density of a solution is equal to the ratio of the mass and volume of solution. Here, mass of benzene can be calculated as m w = ρ × V where m b is the mass of benzene, ρ is the density of benzene, and V is the volume of benzene. Substitute 0 .877 g / mL for ρ and 100 mL for V : m w = 0 .877 g / mL × 100 mL = 87.7 g Mass of benzene is 87.7 g . One gram is equal to 10 − 3 kilograms. Convert grams to kilograms as follows: 87.7 g = 87.7 g × ( 10 − 3 kg 1 g ) = 0.0877 kg Mass of benzene in kilograms is 0.0877 kg . Calculate the number of moles of naphthalene as follows: n n = m n MM n Here, m n is the given mass of naphthalene and MM n is the molar mass of naphthalene. Substitute 10 g for m n and 128.171 g / mol for MM n : n n = 10 g 128.171 g / mol = 0.078 mol So, the number of moles of naphthalene is 0.078 mol . Molality of a solution ( m ) is equal to the ratio of the number of moles of solute (naphthalene) and mass of solvent (benzene) in kilograms. m = n n m b Substitute 0.0877 kg for m b and 0.078 mol for n n : m = 0.078 mol 0.0877 kg = 0.889 m So, the molality of the solution is 0

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

3rd Edition

ISBN: 9780133890686

Author: Tro

Publisher: PEARSON

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Chapter 12, Problem 79E

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To determine: The freezing point and the boiling point of the solution.

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Chapter 12, Problem 78E

Chapter 12, Problem 80E

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Chapter 12 Solutions

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

Ch. 12 - Prob. 1SAQ Ch. 12 - Prob. 2SAQ Ch. 12 - Q3. A 500.0-mL sample of pure water is allowed to...Ch. 12 - Q4. A potassium bromide solution is 7.55 %...Ch. 12 - Prob. 5SAQ Ch. 12 - Prob. 6SAQ Ch. 12 - Prob. 7SAQ Ch. 12 - Prob. 8SAQ Ch. 12 - Prob. 9SAQ Ch. 12 - Prob. 10SAQ

Ch. 12 - Prob. 11SAQ Ch. 12 - Q12. The enthalpy of solution for NaOH is –44.46...Ch. 12 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 12 - Q14. A solution is an equimolar mixture of two...Ch. 12 - Prob. 15SAQ Ch. 12 - Prob. 1E Ch. 12 - Prob. 2E Ch. 12 - Prob. 3E Ch. 12 - Prob. 4E Ch. 12 - Prob. 5E Ch. 12 - Prob. 6E Ch. 12 - Prob. 7E Ch. 12 - Prob. 8E Ch. 12 - Prob. 9E Ch. 12 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 12 - Prob. 11E Ch. 12 - Prob. 12E Ch. 12 - Prob. 13E Ch. 12 - Prob. 14E Ch. 12 - Prob. 15E Ch. 12 - Prob. 16E Ch. 12 - Prob. 17E Ch. 12 - Prob. 18E Ch. 12 - Prob. 19E Ch. 12 - Prob. 20E Ch. 12 - Prob. 21E Ch. 12 - 22. Explain why the lower vapor pressure for a...Ch. 12 - Prob. 23E Ch. 12 - Prob. 24E Ch. 12 - Prob. 25E Ch. 12 - Prob. 26E Ch. 12 - Prob. 27E Ch. 12 - Prob. 28E Ch. 12 - Prob. 29E Ch. 12 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 12 - 31. Which molecule would you expect to be more...Ch. 12 - 32. Which molecule would you expect to be more...Ch. 12 - Prob. 33E Ch. 12 - Prob. 34E Ch. 12 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 12 - 36. When lithium iodide (LiI) is dissolved in...Ch. 12 - Silver nitrate has a lattice energy of 820 kJ/mol...Ch. 12 - Prob. 38E Ch. 12 - Prob. 39E Ch. 12 - Prob. 40E Ch. 12 - Prob. 41E Ch. 12 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 12 - Prob. 43E Ch. 12 - Prob. 44E Ch. 12 - Prob. 45E Ch. 12 - Prob. 46E Ch. 12 - Prob. 47E Ch. 12 - Prob. 48E Ch. 12 - Prob. 49E Ch. 12 - Prob. 50E Ch. 12 - Prob. 51E Ch. 12 - Prob. 52E Ch. 12 - Prob. 53E Ch. 12 - Prob. 54E Ch. 12 - 55. Silver nitrate solutions are often used to...Ch. 12 - Prob. 56E Ch. 12 - Prob. 57E Ch. 12 - Prob. 58E Ch. 12 - Prob. 59E Ch. 12 - Prob. 60E Ch. 12 - Prob. 61E Ch. 12 - Prob. 62E Ch. 12 - Prob. 63E Ch. 12 - Prob. 64E Ch. 12 - Prob. 65E Ch. 12 - Prob. 66E Ch. 12 - Prob. 67E Ch. 12 - Prob. 68E Ch. 12 - Prob. 69E Ch. 12 - Prob. 70E Ch. 12 - 71. Calculate the vapor pressure of a solution...Ch. 12 - Prob. 72E Ch. 12 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 12 - Prob. 74E Ch. 12 - 75. A solution contains 4.08 g of chloroform...Ch. 12 - Prob. 76E Ch. 12 - Prob. 77E Ch. 12 - Prob. 78E Ch. 12 - 79. Calculate the freezing point and boiling point...Ch. 12 - 80. Calculate the freezing point and boiling...Ch. 12 - 81. An aqueous solution containing 17.5 g of an...Ch. 12 - Prob. 82E Ch. 12 - 83. Calculate the osmotic pressure of a solution...Ch. 12 - Prob. 84E Ch. 12 - 85. A solution containing 27.55 mg of an unknown...Ch. 12 - Prob. 86E Ch. 12 - 87. Calculate the freezing point and boiling point...Ch. 12 - Prob. 88E Ch. 12 - Prob. 89E Ch. 12 - Prob. 90E Ch. 12 - Prob. 91E Ch. 12 - Prob. 92E Ch. 12 - Prob. 93E Ch. 12 - Prob. 94E Ch. 12 - 95. A 0.100 M ionic solution has an osmotic...Ch. 12 - Prob. 96E Ch. 12 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 12 - Prob. 98E Ch. 12 - Prob. 99E Ch. 12 - 100. The solubility of phenol in water at 25 °C is...Ch. 12 - Prob. 101E Ch. 12 - Prob. 102E Ch. 12 - Prob. 103E Ch. 12 - Prob. 104E Ch. 12 - Prob. 105E Ch. 12 - Prob. 106E Ch. 12 - Prob. 107E Ch. 12 - 108. The vapor above an aqueous solution contains...Ch. 12 - Prob. 109E Ch. 12 - Prob. 110E Ch. 12 - Prob. 111E Ch. 12 - Prob. 112E Ch. 12 - Prob. 113E Ch. 12 - Prob. 114E Ch. 12 - Prob. 115E Ch. 12 - Prob. 116E Ch. 12 - Prob. 117E Ch. 12 - Prob. 118E Ch. 12 - Prob. 119E Ch. 12 - Prob. 120E Ch. 12 - Prob. 121E Ch. 12 - Prob. 122E Ch. 12 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 12 - Prob. 124E Ch. 12 - Prob. 125E Ch. 12 - Prob. 126E Ch. 12 - 127. A 1.10-g sample contains only glucose...Ch. 12 - 128. A solution is prepared by mixing 631 mL of...Ch. 12 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 12 - Prob. 130E Ch. 12 - Prob. 131E Ch. 12 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 12 - Prob. 133E Ch. 12 - Prob. 134E Ch. 12 - Prob. 135E Ch. 12 - Prob. 136E Ch. 12 - 137. If each substance listed here costs the same...Ch. 12 - Prob. 138E

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