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Chapter 12, Problem 59E
Interpretation Introduction

To determine: The volume of the solution to be diluted.

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AG/F-2° V 3. Before proceeding with this problem you may want to glance at p. 466 of your textbook where various oxo-phosphorus derivatives and their oxidation states are summarized. Shown below are Latimer diagrams for phosphorus at pH values at 0 and 14: -0.93 +0.38 -0.50 -0.51 -0.06 H3PO4 →H4P206 →H3PO3 →→H3PO₂ → P → PH3 Acidic solution Basic solution -0.28 -0.50 3--1.12 -1.57 -2.05 -0.89 PO HPO H₂PO₂ →P → PH3 -1.73 a) Under acidic conditions, H3PO4 can be reduced into H3PO3 directly (-0.28V), or via the formation and reduction of H4P206 (-0.93/+0.38V). Calculate the values of AG's for both processes; comment. (3 points) 0.5 PH P 0.0 -0.5 -1.0- -1.5- -2.0 H.PO, -2.3+ -3 -2 -1 1 2 3 2 H,PO, b) Frost diagram for phosphorus under acidic conditions is shown. Identify possible disproportionation and comproportionation processes; write out chemical equations describing them. (2 points) H,PO 4 S Oxidation stale, N
4. For the following complexes, draw the structures and give a d-electron count of the metal: a) Tris(acetylacetonato)iron(III) b) Hexabromoplatinate(2-) c) Potassium diamminetetrabromocobaltate(III) (6 points)
2. Calculate the overall formation constant for [Fe(CN)6]³, given that the overall formation constant for [Fe(CN)6] 4 is ~1032, and that: Fe3+ (aq) + e = Fe²+ (aq) E° = +0.77 V [Fe(CN)6]³ (aq) + e¯ = [Fe(CN)6] (aq) E° = +0.36 V (4 points)

Chapter 12 Solutions

Masteringchemistry With Pearson Etext -- Valuepack Access Card -- For Principles Of Chemistry: A Molecular Approach

Ch. 12 - Prob. 11SAQCh. 12 - Q12. The enthalpy of solution for NaOH is –44.46...Ch. 12 - Q13. A 2.4 m aqueous solution of an ionic compound...Ch. 12 - Q14. A solution is an equimolar mixture of two...Ch. 12 - Prob. 15SAQCh. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - Prob. 3ECh. 12 - Prob. 4ECh. 12 - Prob. 5ECh. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - 10. What is the heat of hydration (ΔHhydration)?...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - 22. Explain why the lower vapor pressure for a...Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - 30. Pick an appropriate solvent from Table 13.3 to...Ch. 12 - 31. Which molecule would you expect to be more...Ch. 12 - 32. Which molecule would you expect to be more...Ch. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - 35. When ammonium chloride (NH4Cl) is dissolved in...Ch. 12 - 36. When lithium iodide (LiI) is dissolved in...Ch. 12 - Silver nitrate has a lattice energy of 820 kJ/mol...Ch. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - 42. A solution contains 32 g of KNO3 per 100.0 g...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Prob. 49ECh. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - Prob. 52ECh. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - 55. Silver nitrate solutions are often used to...Ch. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Prob. 62ECh. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - Prob. 65ECh. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - Prob. 68ECh. 12 - Prob. 69ECh. 12 - Prob. 70ECh. 12 - 71. Calculate the vapor pressure of a solution...Ch. 12 - Prob. 72ECh. 12 - 73. A solution contains 50.0 g of heptane (C7H16)...Ch. 12 - Prob. 74ECh. 12 - 75. A solution contains 4.08 g of chloroform...Ch. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - Prob. 78ECh. 12 - 79. Calculate the freezing point and boiling point...Ch. 12 - 80. Calculate the freezing point and boiling...Ch. 12 - 81. An aqueous solution containing 17.5 g of an...Ch. 12 - Prob. 82ECh. 12 - 83. Calculate the osmotic pressure of a solution...Ch. 12 - Prob. 84ECh. 12 - 85. A solution containing 27.55 mg of an unknown...Ch. 12 - Prob. 86ECh. 12 - 87. Calculate the freezing point and boiling point...Ch. 12 - Prob. 88ECh. 12 - Prob. 89ECh. 12 - Prob. 90ECh. 12 - Prob. 91ECh. 12 - Prob. 92ECh. 12 - Prob. 93ECh. 12 - Prob. 94ECh. 12 - 95. A 0.100 M ionic solution has an osmotic...Ch. 12 - Prob. 96ECh. 12 - 97. Calculate the vapor pressure at 25 °C of an...Ch. 12 - Prob. 98ECh. 12 - Prob. 99ECh. 12 - 100. The solubility of phenol in water at 25 °C is...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - Prob. 103ECh. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - 108. The vapor above an aqueous solution contains...Ch. 12 - Prob. 109ECh. 12 - Prob. 110ECh. 12 - Prob. 111ECh. 12 - Prob. 112ECh. 12 - Prob. 113ECh. 12 - Prob. 114ECh. 12 - Prob. 115ECh. 12 - Prob. 116ECh. 12 - Prob. 117ECh. 12 - Prob. 118ECh. 12 - Prob. 119ECh. 12 - Prob. 120ECh. 12 - Prob. 121ECh. 12 - Prob. 122ECh. 12 - 123. A 100.0-mL aqueous sodium chloride solution...Ch. 12 - Prob. 124ECh. 12 - Prob. 125ECh. 12 - Prob. 126ECh. 12 - 127. A 1.10-g sample contains only glucose...Ch. 12 - 128. A solution is prepared by mixing 631 mL of...Ch. 12 - 129. Two alcohols, isopropyl alcohol and propyl...Ch. 12 - Prob. 130ECh. 12 - Prob. 131ECh. 12 - 132. A solution of 75.0 g of benzene (C6H6) and...Ch. 12 - Prob. 133ECh. 12 - Prob. 134ECh. 12 - Prob. 135ECh. 12 - Prob. 136ECh. 12 - 137. If each substance listed here costs the same...Ch. 12 - Prob. 138E
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