PRINCIPLES OF MODERN CHEMISTRY-OWLV2
8th Edition
ISBN: 9781305271609
Author: OXTOBY
Publisher: CENGAGE L
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How would you use 'H and 13 C NMR to help you distinguish between these two isomeric structures?
OCH3
CH₁
and
How could you distinguish between the following isomers by 13C-NMR:
a. 1,2-Dimethylbenzene
b. 1,3-Dimethylbenzene
c. 1,4-Dimethylbenzene.
Predict the splitting patterns you would expect for each proton in the molecules below.
a.
septet
c. doublet
H
ΟΞΥ
CH3
b. singlet
d. quartet
2
H
nswer the questions for each of the compounds whose 'H-NMR spectra are shown below.
C4H8O
a.
Describe each signal in terms of its integration, splitting and chemical shift.
b. Propose a structure for this compound.
Is the first carbocation more stable than the second one? If so, why? Isn't an sp2 carbocation more stable than an sp carbocation?
Please correct answer and don't used hand raiting and don't us Ai solution
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- с. d. СнЗ Сизена=-4=4 Cla H Eget3 над f. e. H-C=C-CH3 + 285 → H-C=C-CH3+2не H-C=C-CH3 + Nanta» g+ CH₂ CH₂-G = G-C₁₂-G=CH₂ + 2HI→ H H H ALarrow_forwardThe IR (infrared) spectra of two pure compounds (0.010 M compound A in solvent and 0.010 M compound B in solvent) are given. The pathlength of the cell is 1.00 cm. The y-axis in the spectra is transmittance rather than absorption, so that the wavenumbers at which there is a dip in the curve correspond to absorption peaks. A mixture of A and B in unknown concentrations gave a percent transmittance of 49.8% at 2976 cm¹ and 44.9% at 3030 cm-1 Wavenumber 0.010 M A 0.010 M B Unknown 3030 cm-1 35.0% 93.0% 44.9% 2976 cm-¹ 76.0% 42.0% 49.8% What are the concentrations of A and B in the unknown sample? Transmittance (%) 100 90 80 70 60 50 40 2976 cm-1 30 3030 cm-1 20 Pure A 10 Pure B 0 3040 2990 Wavenumber (cm-1) 2940 2890arrow_forwardsynthesize 1-propyne starting with propane.arrow_forward
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