ORGANIC CHEMISTRY
ORGANIC CHEMISTRY
4th Edition
ISBN: 9781119745105
Author: Klein
Publisher: WILEY
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Chapter 12, Problem 54ASP
Interpretation Introduction

Interpretation:

The compound which does not give 2methyl2pentanol by using Grignard reagent is to be determined.

Concept introduction:

When a Grignard reagent reacts with a carbonyl compound, the alkyl part of the reagent acts as a nucleophile and attacks the electrophilic carbonyl carbon, forming an intermediate compound. This after an acidic aqueous workup yields the product, generally alcohol, depending on the starting carbonyl compound used. The basicity of the Grignard reagent plays an important role in the kinetics and yield of the reaction.

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4. Read paragraph 4.15 from your textbook, use your calculated lattice energy values for CuO, CuCO3 and Cu(OH)2 an explain thermal decomposition reaction of malachite: Cu2CO3(OH)2 →2CuO + H2O + CO2 (3 points)
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