INTRODUCTORY CHEMISTRY
8th Edition
ISBN: 2818000163285
Author: CORWIN
Publisher: PEARSON CO
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Chapter 12, Problem 4CE
Interpretation Introduction
Interpretation:
The statement that corresponds to the formation of a covalent bond between two nonmetal atoms is to be stated.
Concept introduction:
There are two main types of bonding that exist between the compounds. One is an ionic bond and another is a covalent bond. Covalent bonds are formed by the mutual sharing of the electrons between the elements.
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Show that a molecule with configuration π4 has a cylindrically symmetric electron distribution. Hint: Let the π orbitals be equal to xf and yf, where f is a function that depends only on the distance from the internuclear axis.
(a) Verify that the lattice energies of the alkali metal iodides are inversely proportional to the distances between the ions in MI (M = alkali metal) by plotting the lattice energies given below against the internuclear distances dMI. Is the correlation good? Would a better fit be obtained by plotting the lattice energies as a function of (1 — d*/d)/d, as theoretically suggested, with d* = 34.5 pm? You must use a standard graphing program to plot the graph. It generates an equation for the line and calculates a correlation coefficient. (b) From the graph obtained in (a), estimate the lattice energy of silver iodide. (c) Compare the results of (b) with the experimental value of 886 kJ/mol. If they do not agree, explain the deviation.
Can I please get help with #3 & 4? Thanks you so much!
Chapter 12 Solutions
INTRODUCTORY CHEMISTRY
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