(a) Interpretation: The species that is smaller between the pair given is to be predicted. Concept Introduction: Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion. Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases. Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

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Answer

Answer 1

Question

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

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2. Provide a clear arrow-pushing mechanism for the following reactions. Do not skip proton transfers, do not combine steps, and make sure your arrows are clear enough to be interpreted without ambiguity. a. CH3 Ph OEt هد Ph CH3 Hint: the species on the left is an ynolate, which behaves a lot like an enolate.

b. CH3 H3C CH3 CH3 H3C an unexpected product, containing a single 9- membered ring the expected product, containing two fused rings H3C-I (H3C)2CuLi an enolate

Answer 2

Question

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

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Answer 3

Question

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

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Answer 4

Question

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

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Answer 5

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Answer 6

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Answer 7

Chapter 12, Problem 47QAP

Interpretation Introduction

(a)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The species that is smaller between the pair given is to be predicted.

Concept Introduction:

Compounds formed up of ions are known as Ionic compounds. The compound consists of the cation and anion. Cation is the positively charged ion and anion is negatively charged ion.

Cations are always smaller than the atoms from which they are formed because they have less number of electrons than the parent atom due to which the force of attraction between protons and electrons increases and due to this, size decreases.

Anions are always larger than the atoms from which they are formed because they have more number of electrons than the parent atom due to which the repulsion between the electron increases and the force of attraction between protons and electrons decreases and due to this, size increases.

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Solution Summary: The author explains that the species that is smaller between the pair given is to be predicted. Compounds formed up of ions are known as Ionic compounds.

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Chapter 12 Solutions