The product for the given reactions has to be determined. Concept introduction: Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group. Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H 2 O . Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Given the reaction: A(aq) + B(aq) ⇌ 2C(aq) + D(aq). 2.00 moles of each reactant were dissolved into 1.00 literof water. The reaction reached equilibrium, and at equilibrium the concentration of A was 1.60 M.A) Calculate the equilibrium concentrations for each substance. B) Write the equilibrium constant expression. C) Calculate the value for the equilibrium constant, Keq.

1) Draw the structures of D-lysine and L-lysine and assign R/S configuration (showing your workings). 2) Draw the predominant ionisation forms of the free amino acid lysine, at pH 1.0, 8.0, and 11.0. pKa values: 2.2 (-COOH), 9.0 (α-NH3+), 10.5 (side-chain). 3) Calculate (showing your workings) the % of the different ionized species that are present in a 1.00 M solution of L-proline at pH = 10.0. pKa values: 1.95 (- COOH), 10.64 (α-NH3*). 4) a) Draw the tripeptide Tyr-Pro-Lys once with a trans peptide bond between Tyr and Pro and once with a cis peptide bond between Tyr and Pro. b) The electrospray ionization mass spectrum (ESI-MS) of the tripeptide you designed in part (a) shows peaks indicative of mono-protonation and di- protonation of the tripeptide. At what values of m/z would these peaks be expected (no fragmentation)? Briefly explain your answer (showing your workings). 5) How could the sequence of Ala-Met-Thr be distinguished from that of Thr-Ala- Met by tandem ESI-MS-MS?…

LABORATORY REPORT FORM Part I. Determination of the Formula of a Known Hydrate 1. Mass of empty evaporating dish 3. Mass of hydrate Using subtraction or mass by difference, find the mass of the hydrate 76.96 -75.40 75.40g 76.968 1.568 01.56 76.90 g 2. Mass of evaporating dish + hydrate 4. Mass of evaporating dish + hydrate (after heating) First 76.98 g Third 76.66g Second Fourth (if necessary) 76.60g 5. Mass of anhydrate 6. Mass of water lost by the hydrate 7. Percent of water of hydration (Show Calculations) 8. Moles of water (Show Calculations) mol mass of water = MM of water (g/m) 9. Moles of anhydrate (Show Calculations) 10. Ratio of moles of water to moles of anhydrate 11 F(Show Calculations) 11. Formula of hydrate - Mass of water (g) x 100 % water hydration g g % Mass of hydrate (9) x IC % = (Mass of hydrate- mass of an) mass of hydrate (g) % = (1.569- × 100= mol 1.569 mol Mol Mass of anhydrate/MM of anhydrate 12. What was the color of the hydrate? blue What was the color of the…

Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C = O, as their functional group. The carbonyl group in ketones is placed somewhere in the middle of the molecular structure, which means, the C=O is attached to two alkyl groups or benzene rings. Just like all other homologous series, the naming of ketones is done using a common suffix “-one”. The general molecular formula is C n H 2n O. Functional group of a ketone

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

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Answer 5

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 6

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 7

Chapter 12, Problem 47P

(a)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The product for the given reactions has to be determined.

Concept introduction:

Amines are nitrogen-containing organic compounds. They can be defined as derivatives of ammonia where the hydrogen atom is replaced by an alkyl or aryl group.

Amines react with carbonyl compounds like ketone to form an imine or an enamine. The reaction is a nucleophilic addition reaction with a loss of smaller molecule like H2O.

Amines also react with acyl chloride to form an amide. The reaction is generally a nucleophilic substitution reaction where chloride group acts as a good leaving group.

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 12.1 - Prob. 1P Ch. 12.1 - Name the following compounds:Ch. 12.1 - Prob. 3P Ch. 12.1 - Prob. 4P Ch. 12.2 - Prob. 5P Ch. 12.4 - Draw the structure for each of the following: a....Ch. 12.4 - Prob. 7P Ch. 12.5 - What products are formed when the following...Ch. 12.5 - Prob. 9P Ch. 12.5 - Prob. 10P

Solution Summary: The author explains that amines are nitrogen-containing organic compounds that react with carbonyl compounds like ketone to form an imine or an enamine.

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Chapter 12 Solutions