ORGANIC CHEM PRINT STUDY GDE & SSM
ORGANIC CHEM PRINT STUDY GDE & SSM
4th Edition
ISBN: 9781119810650
Author: Klein
Publisher: WILEY
Question
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Chapter 12, Problem 46PP

(a)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: Sodium dichromate (Na2Cr2O7) is used to oxidize secondary alcohols to ketones. It is a very strong oxidant.

(b)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: PCC oxidizes 1° alcohols into aldehydes and secondary alcohols into ketones. PCC does not convert aldehydes into carboxylic acids, in contrast to chromic acid.

(c)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: PCC oxidizes 1° alcohols into aldehydes and secondary alcohols into ketones. PCC does not convert aldehydes into carboxylic acids, in contrast to chromic acid.

(d)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: Sodium dichromate (Na2Cr2O7) is a chromic acid reagent, used to oxidize secondary alcohols to ketones. It is a very strong oxidant.

(e)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction: With the aid of reagents like sodium borohydride or lithium aluminum hydride, aldehydes and ketones can undergo a reduction process to produce either primary alcohol or secondary alcohol.

(f)

Interpretation Introduction

Interpretation: The reagent used in the given reaction is to be identified.

Concept introduction:

With the aid of reagents like sodium borohydride or lithium aluminum hydride, aldehydes and ketones can undergo a reduction process to produce either primary alcohol or secondary alcohol.

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3. 2. 1. On the graph below, plot the volume of rain in milliliters versus its height in centimeters for the 400 mL beaker. Draw a straight line through the points and label it "400 mL beaker." Volume (mL) 400 350 300 250 200 150 750 mL Florence Volume Versus Height of Water 400 mL beaker 100 50 0 0 2 3 4 5 Height (cm) 6 7 8 9 10 Explain why the data points for the beaker lie roughly on a straight line. What kind of relationship is this? How do you know? (see page 276 text) the design of the beaker is a uniform cylinder the volume of liquid increases evenly with its height resulting in a linear relationship. What volume would you predict for 10.0 cm of water? Explain how you arrived at your answer. Use the data table and the graph to assist you in answering the question. 4. Plot the volume of rain in milliliters versus its height in centimeters for the 250 mL Florence flask on the same graph. Draw a best-fit curve through the points and label it "250 mL Florence flask." oke came
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