Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card
6th Edition
ISBN: 9781305717367
Author: Mark S. Cracolice, Ed Peters
Publisher: Cengage Learning
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Chapter 12, Problem 44E
Interpretation Introduction

(a)

Interpretation:

The reason as to why the total energy of a system changes in the formation of an ionic bond is to be stated.

Concept introduction:

An ionic bond is formed by the transfer of electrons, which is also known as electrovalent bond. Ionic bonds are formed between electropositive and electronegative elements, which have larger electronegativity difference.

Interpretation Introduction

(b)

Interpretation:

The reason as to why the total energy of a system changes in the formation of a covalent bond is to be stated.

Concept introduction:

A covalent bond is formed by the mutual sharing of electrons. The number of electrons contributed by each atom is known as covalence of the atom. The covalent bond is stronger than ionic bonds because of the sharing of electrons.

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Relative Intensity Part VI. consider the multi-step reaction below for compounds A, B, and C. These compounds were subjected to mass spectrometric analysis and the following spectra for A, B, and C was obtained. Draw the structure of B and C and match all three compounds to the correct spectra. Relative Intensity Relative Intensity 100 HS-NJ-0547 80 60 31 20 S1 84 M+ absent 10 30 40 50 60 70 80 90 100 100- MS2016-05353CM 80- 60 40 20 135 137 S2 164 166 0-m 25 50 75 100 125 150 m/z 60 100 MS-NJ-09-43 40 20 20 80 45 S3 25 50 75 100 125 150 175 m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following: (a) match structures of isomers given their mass spectra below (spectra A and spectra B) (b) Draw the fragments given the following prominent peaks from each spectrum: Spectra A m/2 =43 and 1/2-57 spectra B m/2 = 43 (c) why is 1/2=57 peak in spectrum A more intense compared to the same peak in spectrum B. Relative abundance Relative abundance 100 A 50 29 29 0 10 -0 -0 100 B 50 720 30 41 43 57 71 4-0 40 50 60 70 m/z 43 57 8-0 m/z = 86 M 90 100 71 m/z = 86 M -O 0 10 20 30 40 50 60 70 80 -88 m/z 90 100

Chapter 12 Solutions

Bundle: Introductory Chemistry: An Active Learning Approach, 6th + OWLv2, 1 term (6 months) Printed Access Card

Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - Prob. 13ECh. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - Prob. 17ECh. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Prob. 21ECh. 12 - Consider the following bonds: GeSe, BrSe, BrGe....Ch. 12 - Prob. 23ECh. 12 - Consider the following bonds: TeSe, OTe, OSe....Ch. 12 - Prob. 25ECh. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - What is the maximum number of atoms to which a...Ch. 12 - Prob. 31ECh. 12 - Prob. 32ECh. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Prob. 36ECh. 12 - Prob. 37ECh. 12 - Prob. 38ECh. 12 - Prob. 39ECh. 12 - Prob. 40ECh. 12 - Prob. 41ECh. 12 - Prob. 42ECh. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - Prob. 45ECh. 12 - Prob. 46ECh. 12 - Prob. 47ECh. 12 - Prob. 48ECh. 12 - Which orbitals of each atom overlap in forming a...Ch. 12 - Prob. 50ECh. 12 - Prob. 51ECh. 12 - A monatomic ion with a 2 charge has the electron...Ch. 12 - Prob. 53ECh. 12 - Prob. 54ECh. 12 - Prob. 55ECh. 12 - Prob. 56ECh. 12 - Prob. 57ECh. 12 - Prob. 58ECh. 12 - Prob. 59ECh. 12 - Prob. 60ECh. 12 - Prob. 61ECh. 12 - Which ions among the following are isoelectronic...Ch. 12 - Prob. 12.2TCCh. 12 - Prob. 12.3TCCh. 12 - Prob. 12.4TCCh. 12 - Prob. 12.5TCCh. 12 - Prob. 1CLECh. 12 - Prob. 2CLECh. 12 - Prob. 3CLECh. 12 - Prob. 4CLECh. 12 - Prob. 5CLECh. 12 - Prob. 6CLECh. 12 - Write the electron configurations for the oxide...Ch. 12 - Arrange the following bonds in order of decreasing...
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