INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
6th Edition
ISBN: 9780134809922
Author: Tro
Publisher: PEARSON
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Textbook Question
Chapter 12, Problem 41E
Which causes a more severe burn: spilling 0.50 g of 100 °C water on your hand or allowing 0.50 g of 100 °C steam to condense on your hand? Why?
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Solution
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Use retrosynthetic analysis to suggest two paths to synthesize 2-methyl-3-hexanol using the Grignard reaction. (Click and drag
the appropriate image to the correct position in the reactions.)
Route 1
Aldehyde 1
or
+98
Aldehyde 2
Route 2
Q6
+100
Solved in 1 attempt
Q7
+95
Solved in 2 attempts
Q8
+98
Unlimited attempts
possible
+
+
Grignard 1
OH
H3O+
Grignard 2
Answer Bank
Q9
+90
MgBr
Unlimited attempts
possible
CH3CH2CH2MgBr
Q10
Unlimited attempts
Q11
?
?
+100
in 1 attempt
2-methyl-3-hexanol
CH3CH2MgBr
H
H
о
H
Attempt 3
2) (4 pt) After the reaction was completed, the student collected the following data. Crude
product data is the data collected after the reaction is finished, but before the product
is purified. "Pure" product data is the data collected after attempted purification using
recrystallization.
Student B's data:
Crude product data
"Pure"
product data
after
recrystallization
Crude mass: 0.93 g grey solid
Crude mp: 96-106 °C
Crude % yield:
Pure mass: 0.39 g white solid
Pure mp: 111-113 °C
Pure % yield:
a) Calculate the crude and pure percent yields for the student's reaction.
b) Summarize what is indicated by the crude and pure melting points.
Don't used hand raiting
Chapter 12 Solutions
INTRODUCTORY CHEMISTRY-W/MOD.MASTERING.
Ch. 12 - The first diagram shown here represents liquid...Ch. 12 - Prob. 2SAQCh. 12 - Prob. 3SAQCh. 12 - How many 20.0-g ice cubes are required to absorb...Ch. 12 - Prob. 5SAQCh. 12 - Prob. 6SAQCh. 12 - Prob. 7SAQCh. 12 - Prob. 8SAQCh. 12 - Prob. 9SAQCh. 12 - Prob. 10SAQ
Ch. 12 - Prob. 1ECh. 12 - Prob. 2ECh. 12 - What determines whether a substance is a solid,...Ch. 12 - 4. What are the properties of liquids? Explain the...Ch. 12 - 5. What are the properties of solids? Explain the...Ch. 12 - Prob. 6ECh. 12 - Prob. 7ECh. 12 - Prob. 8ECh. 12 - Prob. 9ECh. 12 - Why does a glass of water evaporate more slowly in...Ch. 12 - Prob. 11ECh. 12 - Prob. 12ECh. 12 - 13. Acetone evaporates more quickly than water at...Ch. 12 - Prob. 14ECh. 12 - Prob. 15ECh. 12 - Prob. 16ECh. 12 - 17. Explain why a steam burn from gaseous water at...Ch. 12 - Prob. 18ECh. 12 - Prob. 19ECh. 12 - Prob. 20ECh. 12 - Is the melting of ice endothermic or exothermic?...Ch. 12 - 22. Is the boiling of water endothermic or...Ch. 12 - Prob. 23ECh. 12 - Prob. 24ECh. 12 - 25. What is hydrogen bonding? How can you tell...Ch. 12 - Prob. 26ECh. 12 - Prob. 27ECh. 12 - Prob. 28ECh. 12 - Prob. 29ECh. 12 - Prob. 30ECh. 12 - Prob. 31ECh. 12 - 32. What is an atomic solid? What are the...Ch. 12 - Prob. 33ECh. 12 - Prob. 34ECh. 12 - Prob. 35ECh. 12 - Two samples of pure water of equal volume are put...Ch. 12 - Prob. 37ECh. 12 - Spilling water over your skin on a hot day will...Ch. 12 - Prob. 39ECh. 12 - Water is put into a beaker and heated with a...Ch. 12 - 41. Which causes a more severe burn: spilling 0.50...Ch. 12 - 42. The nightly winter temperature drop in a...Ch. 12 - Prob. 43ECh. 12 - Prob. 44ECh. 12 - 45. An ice chest is filled with 3.5 kg of ice at...Ch. 12 - Why does 50 g of water initially at 0 C warm more...Ch. 12 - In Denver, Colorado, water boils at 95. C....Ch. 12 - Prob. 48ECh. 12 - 49. How much heat is required to vaporize 33.8 g...Ch. 12 - How much heat is required to vaporize 43.9 g of...Ch. 12 - How much heat does your body lose when 2.8 g of...Ch. 12 - How much heat does your body lose when 4.86 g of...Ch. 12 - How much heat is emitted when 4.25 g of water...Ch. 12 - Prob. 54ECh. 12 - 55. The human body obtains 835 kJ of energy from a...Ch. 12 - 56. The human body obtains 1078 kJ from a candy...Ch. 12 - How much heat is required to melt 37.4 g of ice at...Ch. 12 - 58. How much heat is required to melt 23.9 g of...Ch. 12 - How much energy is released when 34.2 g of water...Ch. 12 - How much energy is released when 2.55 kg of...Ch. 12 - 61. How much heat is required to convert 2.55 g of...Ch. 12 - 62. How much heat is required to convert 5.88 g of...Ch. 12 - Prob. 63ECh. 12 - Prob. 64ECh. 12 - 65. What kinds of intermolecular forces are...Ch. 12 - Prob. 66ECh. 12 - Prob. 67ECh. 12 - What kinds of intermolecular forces are present in...Ch. 12 - Which substance has the highest boiling point?...Ch. 12 - Prob. 70ECh. 12 - One of these two substances is a liquid at room...Ch. 12 - Prob. 72ECh. 12 - 73. A flask containing a mixture of and is...Ch. 12 - 74. Explain why is a liquid at room temperature...Ch. 12 - Are CH3CH2CH2CH2CH3 and H2O miscible?Ch. 12 - Prob. 76ECh. 12 - Prob. 77ECh. 12 - 78. Determine whether a homogeneous solution forms...Ch. 12 - 79. Identify each solid as molecular, ionic, or...Ch. 12 - Prob. 80ECh. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - Identify each solid as molecular, ionic, or...Ch. 12 - 83. Which solid has the highest melting point?...Ch. 12 - 84. Which solid has the highest melting point?...Ch. 12 - 85. For each pair of solids, determine which solid...Ch. 12 - For each pair of solids, determine which solid has...Ch. 12 - 87. List these substances in order of increasing...Ch. 12 - 88. List these substances in order of decreasing...Ch. 12 - 89. Ice actually has negative caloric content. How...Ch. 12 - Prob. 90ECh. 12 - An 8.5-g ice cube is placed into 255 g of water....Ch. 12 - A 14.7-g ice cube is placed into 324 g of water....Ch. 12 - 93. How much ice in grams would have to melt to...Ch. 12 - Prob. 94ECh. 12 - Prob. 95ECh. 12 - Prob. 96ECh. 12 - Draw a Lewis structure for each molecule and...Ch. 12 - Draw a Lewis structure for each molecule and...Ch. 12 - 99. The melting point of ionic solids depends on...Ch. 12 - Draw ionic Lewis structures for KF and CaO. Use...Ch. 12 - Prob. 101ECh. 12 - Prob. 102ECh. 12 - An ice cube at 0.00 C with a mass of 23.5 g is...Ch. 12 - Prob. 104ECh. 12 - Prob. 105ECh. 12 - Prob. 106ECh. 12 - Prob. 107ECh. 12 - Prob. 108ECh. 12 - Prob. 109QGWCh. 12 - Prob. 110QGWCh. 12 - Prob. 111QGWCh. 12 - Prob. 112QGWCh. 12 - Prob. 113DIA
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- A DEPT NMR spectrum is shown for a molecule with the molecular formula of C5H12O. Draw the structure that best fits this data. 200 180 160 140 120 100 一盆 00 40 8- 20 ppm 0 Qarrow_forwardDon't used hand raitingarrow_forwardShown below is the major resonance structure for a molecule. Draw the second best resonance structure of the molecule. Include all non-zero formal charges. H. H. +N=C H H H Cl: Click and drag to start drawing a structure. : ? g B S olo Ar B Karrow_forward
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