EBK ORGANIC CHEMISTRY AS A SECOND LANGU
EBK ORGANIC CHEMISTRY AS A SECOND LANGU
3rd Edition
ISBN: 9781118203774
Author: Klein
Publisher: YUZU
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Chapter 12, Problem 32PP

(a)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Bromination:

Alcohols brominated by using PBr3 which provides corresponding brominated products.

(b)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

(c)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Chlorination:

Alcohols chlorinated by using thionyl chloride and pyridine which provides corresponding chlorinated products.

Similarly, alcohols can be chlorinated by using hydrochloric acid and zinc chloride which provides corresponding chlorinated products.

(d)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Oxidation Reaction: The Dess-Martin Periodinane (DMP), a hyper valent iodine compound, offers selective and very mild oxidation of alcohols to aldehydes.

(e)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Oxidation: Alcohols undergoing oxidation by using oxidizing agent like PCC (Pyridinium Chlorochromate) in dichloromethane which provides aldehyde.

Alcohols undergoing oxidation by using oxidizing agent like Na2Cr2O7(chromic acid) which provides carboxylic acid.

(f)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Alcohols treated with any metals or base which provides alkoxide.

(g)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Alcohols treated with any metals or base which provides alkoxide.

(h)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

(i)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Alcohols is protected by using variety of reaction for example, Alcohols can be protected by treating with tosyl chloride in presence of base. Similarly it can be protected by using TMSCl in presence of base.

(j)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Alcohols treated with any metals or base which provides alkoxide.

(k)

Interpretation Introduction

Interpretation:

The major product for the given reaction should be identified.

Concept introduction:

Alcohols treated with any metals or base which provides alkoxide.

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Chapter 12 Solutions

EBK ORGANIC CHEMISTRY AS A SECOND LANGU

Ch. 12.4 - Prob. 3LTSCh. 12.4 - Prob. 9PTSCh. 12.4 - Prob. 10ATSCh. 12.4 - Prob. 4LTSCh. 12.4 - Prob. 11PTSCh. 12.4 - Prob. 12ATSCh. 12.6 - Prob. 5LTSCh. 12.6 - Prob. 13PTSCh. 12.6 - Prob. 14PTSCh. 12.7 - Prob. 16CCCh. 12.9 - Prob. 6LTSCh. 12.9 - Prob. 17PTSCh. 12.9 - Prob. 18ATSCh. 12.9 - Prob. 19CCCh. 12.10 - Prob. 7LTSCh. 12.10 - PRACTICE the skill Predict the major organic...Ch. 12.10 - Prob. 21ATSCh. 12.13 - Prob. 8LTSCh. 12.13 - Prob. 22PTSCh. 12.13 - Prob. 23ATSCh. 12.13 - Prob. 24CCCh. 12.13 - Prob. 9LTSCh. 12.13 - Prob. 25PTSCh. 12.13 - Prob. 26ATSCh. 12 - Prob. 27PPCh. 12 - Prob. 28PPCh. 12 - Prob. 29PPCh. 12 - Prob. 30PPCh. 12 - Prob. 31PPCh. 12 - Predict the major product of the reaction between...Ch. 12 - Prob. 33PPCh. 12 - Prob. 34PPCh. 12 - Using a Grignard reaction, show how you could...Ch. 12 - Each of the following alcohols can be prepared via...Ch. 12 - Prob. 37PPCh. 12 - Prob. 38PPCh. 12 - Prob. 39PPCh. 12 - Prob. 40PPCh. 12 - Prob. 41PPCh. 12 - Prob. 42PPCh. 12 - Prob. 43PPCh. 12 - Prob. 44PPCh. 12 - Prob. 45PPCh. 12 - Prob. 46PPCh. 12 - Prob. 47PPCh. 12 - Prob. 48PPCh. 12 - Prob. 49PPCh. 12 - Prob. 50PPCh. 12 - Prob. 51IPCh. 12 - Prob. 52IPCh. 12 - Prob. 53IPCh. 12 - Prob. 54IPCh. 12 - Prob. 55IPCh. 12 - Prob. 56IPCh. 12 - Prob. 57IPCh. 12 - Prob. 58IPCh. 12 - Prob. 59IPCh. 12 - Prob. 60IPCh. 12 - Prob. 61IPCh. 12 - Prob. 62IPCh. 12 - Prob. 63IPCh. 12 - Prob. 64IPCh. 12 - Prob. 65IPCh. 12 - The compound duryne was one of several...Ch. 12 - Estragole is an insect repellant that has been...Ch. 12 - Prob. 68IPCh. 12 - Prob. 70IPCh. 12 - Prob. 71IPCh. 12 - Prob. 72IPCh. 12 - Prob. 73IPCh. 12 - Prob. 74IPCh. 12 - Prob. 75CPCh. 12 - Prob. 76CPCh. 12 - Prob. 77CP
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