EBK ORGANIC CHEMISTRY
EBK ORGANIC CHEMISTRY
7th Edition
ISBN: 9780133556186
Author: Bruice
Publisher: VST
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Chapter 12, Problem 29P
Interpretation Introduction

Interpretation:

The vinyl halides required to synthesize each of the given compounds by Heck coupling has to be determined.

Concept introduction:

  • Organometallic compound it can be defined as the compound which contain Carbon – Metal bond.
  • The carbon attached to the halogen in an alkyl halide is an electrophile, whereas the carbon attached to the metal in an organometallic compound is a nucleophile.
  • Heck reaction: A reaction that couples an aryl halide or vinyl halide with an alkene.
  • Grignard reagent:

The compound that results when magnesium is inserted between the carbon atom and the halogen of an alkyl halide like RMgBr & RMgCl 

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Г C-RSA CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.0 b.092 0.797 1.088 1.813 C-RSA CHROMATOPAC CH=1 Report No. =13 ** CALCULATION REPORT ** DATA=1: @CHRM1.000 11/03/05 08:09:52 CH PKNO TIME 1 2 0.797 3 1.088 4 1.813 AREA 1508566 4625442 2180060 HEIGHT 207739 701206 V 287554 V MK IDNO CONC NAME 18.1447 55.6339 26.2213 TOTAL 8314067 1196500 100 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0. 0 087 337. 0.841 1.150 C-R8A CHROMATOPAC CH=1 Report No. =14 DATA=1: @CHRM1.000 11/03/05 08:12:40 ** CALCULATION REPORT ** CH PKNO TIME AREA 1 3 0.841 1099933 41.15 4039778 HEIGHT MK IDNO 170372 649997¯¯¯ CONC NAME 21.4007 78.5993 TOTAL 5139711 820369 100 3 C-R8A CHROMATOPAC CH=1 DATA 1: @CHRM1.C00 ATTEN=10 SPEED= 10.0 0.100 0:652 5.856 3 1.165 C-RSA CHROMATOPAC CH-1 Report No. =15 DATA=1: @CHRM1.000 11/03/05 08:15:26 ** CALCULATION REPORT ** CH PKNO TIME AREA HEIGHT MK IDNO CONC NAME 1 3 3 0.856 4 1.165 TOTAL 1253386 4838738 175481 708024 V 20.5739 79.4261 6092124…
Draw the product of the reaction shown below. Ignore small byproducts that would evaporate please.
Relative Abundance 20- Problems 501 (b) The infrared spectrum has a medium-intensity peak at about 1650 cm. There is also a C-H out-of-plane bending peak near 880 cm. 100- 80- 56 41 69 M(84) LL 15 20 25 30 35 55 60 65 70 75 80 85 90 m/z
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