Products of the given reaction have to be determined. Concept introduction: Suzuki reaction: A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent . Heck reaction: A reaction that breaks the double bond of alkene and then joins the fragments . Organoboron compound: An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R ' B ( OR ) 2 . Coupling reaction: A reaction that joins two groups with a carbon-carbon bond.

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Answer 1

Question

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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If a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.

Answer 2

Question

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Answer 3

Question

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Answer 4

Question

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Answer 5

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 6

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 7

Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 8

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 9

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 10

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 11

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 12

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 13

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 14

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 15

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 16

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 17

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

Answer 18

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Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 12.1 - Prob. 1P Ch. 12.2 - Which is more reactive an organolithium compound...Ch. 12.2 - Prob. 3P Ch. 12.3 - PROBLEM 6♦ Explain why tertiary alkyl halides...Ch. 12.3 - Muscalure is the sex attractant of the common...Ch. 12.3 - Prob. 8P Ch. 12.3 - Prob. 9P Ch. 12.3 - Prob. 10P Ch. 12.4 - Prob. 13P Ch. 12.4 - Prob. 14P

Solution Summary: The author introduces Suzuki reaction, which couples an aryl or vinyl halide with an Organoboron reagent. Heck reaction breaks the double bond of alkene and joins the fragments.

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Chapter 12 Solutions