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Chapter 12, Problem 28P

(a)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(b)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an Organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(c)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of sa alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(d)

Interpretation Introduction

Interpretation:

Products of the given reaction have to be determined.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(e)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be written.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound:  R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

(f)

Interpretation Introduction

Interpretation:

Product of the given reaction has to be identified.

Concept introduction:

Suzuki reaction:

A reaction that couples an aryl halide or vinyl halide with an organoboron reagent.

Heck reaction:

A reaction that breaks the double bond of an alkene and then joins the fragments.

Organoboron compound:

An alkyl –organoboron compound, an alkenyl –Organoboron compound, or an aryl –Organoboron compound: R'B(OR)2.

Coupling reaction:

A reaction that joins two groups with a carbon-carbon bond.

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Chapter 12 Solutions

Organic Chemistry; Modified MasteringChemistry with Pearson eText -- ValuePack Access Card; Study Guide and Student Solutions Manual for Organic Chemistry, Books a la Carte Edition (7th Edition)

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