Alcohol is removed from the bloodstream by a series of metabolic reactions. The first reaction produces acetaldehyde; then other products are formed. The following data have been determined for the rate at which alcohol is removed from the blood of an average male, although individual rates can vary by 25−30%. Women metabolize alcohol a little more slowly than men: [C 2 H 5 OH]( M ) 4.4 × 10 − 2 3.3 × 10 − 2 2.2 × 10 − 2 Rate(moI/L/h) 2.0 × 10 − 2 2.0 × 10 − 2 2.0 × 10 − 2 Determine the rate equation, the rate constant, and the overall order for this reaction.
Alcohol is removed from the bloodstream by a series of metabolic reactions. The first reaction produces acetaldehyde; then other products are formed. The following data have been determined for the rate at which alcohol is removed from the blood of an average male, although individual rates can vary by 25−30%. Women metabolize alcohol a little more slowly than men: [C 2 H 5 OH]( M ) 4.4 × 10 − 2 3.3 × 10 − 2 2.2 × 10 − 2 Rate(moI/L/h) 2.0 × 10 − 2 2.0 × 10 − 2 2.0 × 10 − 2 Determine the rate equation, the rate constant, and the overall order for this reaction.
Alcohol is removed from the bloodstream by a series of metabolic reactions. The first reaction produces acetaldehyde; then other products are formed. The following data have been determined for the rate at which alcohol is removed from the blood of an average male, although individual rates can vary by 25−30%. Women metabolize alcohol a little more slowly than men:
[C2H5OH](M)
4.4
×
10
−
2
3.3
×
10
−
2
2.2
×
10
−
2
Rate(moI/L/h)
2.0
×
10
−
2
2.0
×
10
−
2
2.0
×
10
−
2
Determine the rate equation, the rate constant, and the overall order for this reaction.
Definition Definition Study of the speed of chemical reactions and other factors that affect the rate of reaction. It also extends toward the mechanism involved in the reaction.
Indicate how to find the energy difference between two levels in cm-1, knowing that its value is 2.5x10-25 joules.
The gyromagnetic ratio (gamma) for 1H is 2.675x108 s-1 T-1. If the applied field is 1,409 T what will be the separation between nuclear energy levels?
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11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
• 6H total $4th total
Statistical
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21 total
2 H
A 2H
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a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
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Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl