ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.)
4th Edition
ISBN: 9781119761068
Author: Klein
Publisher: WILEY
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Chapter 1.2, Problem 1.6P
Interpretation Introduction

Interpretation:

A systematic name for the given compound has to be provided.

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 1.2, Problem 1.6P , additional homework tip  1

Concept Introduction:

Nomenclature of aromatic compounds:

  • The parent is benzene ring.  Functional groups attached to it other than hydrogens are called substituents.  The name of substituent must be placed before the name of the compound as a prefix in any substituted hydrocarbon.

    Ex.

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 1.2, Problem 1.6P , additional homework tip  2

  • The numerical prefixes such as di, tri, and tetra must be included in the nomenclature if more than one similar substituents are attached to the benzene ring.

    Ex.

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 1.2, Problem 1.6P , additional homework tip  3

  • If different substituent groups are attached to the benzene ring, the no. one position is determined by the parent.  So the first step is to choose a suitable parent.  Then the locants are assigned in a manner that gives the lower possible number to the next substituent.

    Ex.

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 1.2, Problem 1.6P , additional homework tip  4

  • For disubstituted benzenes, prefixes such as ortho, meta and para should be used.

    Ex.

ORGANIC CHEMISTRY-NEXTGEN+BOX (2 SEM.), Chapter 1.2, Problem 1.6P , additional homework tip  5

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0
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