The decomposition of NH 4 HS , NH 4 HS ( s ) ⇄ NH 3 ( g ) + H 2 S ( g ) is an endothermic process. Using Le principle, explain how increasing the temperature would affect the equilibrium. If more NH 4 HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH 3 is placed in the flask? What will happen to the pressure of NH 3 if some H 2 S is removed from the flask?
The decomposition of NH 4 HS , NH 4 HS ( s ) ⇄ NH 3 ( g ) + H 2 S ( g ) is an endothermic process. Using Le principle, explain how increasing the temperature would affect the equilibrium. If more NH 4 HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH 3 is placed in the flask? What will happen to the pressure of NH 3 if some H 2 S is removed from the flask?
Solution Summary: The author explains that an endothermic reaction is a reaction in which energy is consumed or added to the reaction. The effect of removal of H 2 S on the pressure of NH3 should be explained.
is an endothermic process. Using Le principle, explain how increasing the temperature would affect the equilibrium. If more
NH
4
HS
is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional
NH
3
is placed in the flask? What will happen to the pressure of
NH
3
if some
H
2
S
is removed from the flask?
Part VII. The H-NMR of a compound with molecular formula C5 H 10 O2 is given below.
Find the following:
(a) The no. of protons corresponding to each signal in the spectra
(6) Give the structure of the compound and assign the signals to each
proton in the compound.
a
70.2
Integration Values
C5H10O2
b
47.7
C
46.5
d
69.5
3.6 3.5
3.4 3.3 3.2 3.1 3.0
2.9 2.8
2.7
2.6 2.5
2.4 2.3 2.2 2.1 2.0
Chemical Shift (ppm)
1.9
1.8
1.7 1.6
1.5
1.4 1.3 1.2
1.1 1.0
0.9 0.8
Part 111. 1 H-NMR spectrum of a compound with integration values in red is given below.
Answer the following:
(a) write the signals in the 'H-NMR spectrum to the corresponding protons on the structure
of the molecule below.
(b) Identify the theoretical multiplicities for each proton in the compound. Also give the possible.
complex splitting patterns assuming J values are not similar.
там
Br
22
2
3
6
4 7.2 7.0 6.8 6.6 6.4 6.2 6.0 5.8 5.6 5.4 5.2 5.0 4.8 4.6 4.4 4.2 4.0 3.8 3.6 3.4 3.2 3.0 2.8 2.6 2.4 2.2 2.0 1.8 1.6 1.4 1.2 1.0 0.8 0
Chemical Shift (ppm)
ra.
Br
2
3
6
6
2.5
2.4
2.3
2.2
2.1
2.0
1.9
1.8
1.7
1.6
1.5
1.4
1.3
1.2
1.1
1.0
0.9
0.8
Chemical Shift (ppm)
2
2
Br
7.3
7.2
7.1
7.0 6.9
6.7 6.6 6.5
6.4
6.3
6.2
6.1
6.0
Chemical Shift (ppm)
5.9
5.8 5.7
5.5 5.4 5.3 5.2
5.0 4.9
1600°
1538°C
1493°C
In the diagram, the letter L indicates
that it is a liquid. Indicate its
components in the upper region
where only L is indicated.
The
iron-iron carbide phase
diagram.
Temperature (°C)
1400
8
1394°C
y+L
1200
2.14
y, Austenite
10000
912°C
800a
0.76
0.022
600
400
(Fe)
a, Ferrite
Composition (at% C)
15
1147°C
a + Fe3C
2
3
Composition (wt% C)
L
2500
4.30
2000
y + Fe3C
727°C
1500
Cementite (Fe3C)
1000
4
5
6
6.70
Temperature (°F)
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