EBK CHEMISTRY FOR ENGINEERING STUDENTS,
4th Edition
ISBN: 9781337671439
Author: Holme
Publisher: CENGAGE LEARNING - CONSIGNMENT
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Chapter 12, Problem 12.6PAE
Interpretation Introduction
Interpretation:
The
Concept Introduction:
- Concrete is a mixture of cement, water and other additives that are mixed in order to produce concrete with the desired composition and characteristics.
- Production of concrete releases CO2 into the atmosphere where weathering or hardening proceeds with the absorption of CO2
- Carbonation generally involves reactions of carbon dioxide to form carbonates, bicarbonates or carbonic acid.
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Relative Intensity
Part VI. consider the multi-step reaction below for compounds
A, B, and C.
These compounds were subjected to mass spectrometric analysis and
the following spectra for A, B, and C was obtained.
Draw the structure of B and C and match all three compounds
to the correct spectra.
Relative Intensity
Relative Intensity
100
HS-NJ-0547
80
60
31
20
S1
84
M+
absent
10
30
40
50
60
70
80
90
100
100-
MS2016-05353CM
80-
60
40
20
135 137
S2
164 166
0-m
25
50
75
100
125
150
m/z
60
100
MS-NJ-09-43
40
20
20
80
45
S3
25
50
75
100
125
150
175
m/z
Part II. Given two isomers: 2-methylpentane (A) and 2,2-dimethyl butane (B) answer the following:
(a) match structures of isomers given their mass spectra below (spectra A and spectra B)
(b) Draw the fragments given the following prominent peaks from
each spectrum:
Spectra A m/2 =43 and 1/2-57
spectra B m/2 = 43
(c) why is 1/2=57 peak in spectrum A more intense compared
to the same peak in spectrum B.
Relative abundance
Relative abundance
100
A
50
29
29
0
10
-0
-0
100
B
50
720
30
41
43
57
71
4-0
40
50
60 70
m/z
43
57
8-0
m/z = 86
M
90 100
71
m/z = 86
M
-O
0
10 20 30
40 50
60
70
80
-88
m/z
90
100
Chapter 12 Solutions
EBK CHEMISTRY FOR ENGINEERING STUDENTS,
Ch. 12 - list chemical reactions important in the...Ch. 12 - Explain that equilibrium is dynamic, and that at...Ch. 12 - Prob. 3COCh. 12 - calculate equilibrium constants from experimental...Ch. 12 - Prob. 5COCh. 12 - calculate molar solubility from Kspor vice versa.Ch. 12 - Prob. 7COCh. 12 - Prob. 8COCh. 12 - calculate the new equilibrium composition of a...Ch. 12 - Explain the importance of both kinetic and...
Ch. 12 - Identify the first chemical step in the production...Ch. 12 - Explain why the hydration process for concrete is...Ch. 12 - Prob. 12.3PAECh. 12 - 12.4 In what geographical region of the country...Ch. 12 - Prob. 12.5PAECh. 12 - Prob. 12.6PAECh. 12 - Prob. 12.7PAECh. 12 - On your desk is a glass half-filled with water and...Ch. 12 - An equilibrium involving the carbonate and...Ch. 12 - A small quantity of a soluble salt is placed in...Ch. 12 - Prob. 12.11PAECh. 12 - Prob. 12.12PAECh. 12 - Write equilibrium (mass action) expressions for...Ch. 12 - What is the difference between homogeneous...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - Write equilibrium expressions for each of the...Ch. 12 - 12.17 Which of the following is more likely to...Ch. 12 - The reaction, 3 H2(g) + N2(g) (g), has the fol...Ch. 12 - 12.19 For each of the following equations, write...Ch. 12 - Consider the following equilibria involving SO2(g)...Ch. 12 - Prob. 12.21PAECh. 12 - Prob. 12.22PAECh. 12 - Prob. 12.23PAECh. 12 - Prob. 12.24PAECh. 12 - Prob. 12.25PAECh. 12 - The following data were collected for the...Ch. 12 - The following data were collected for a system at...Ch. 12 - Prob. 12.28PAECh. 12 - Nitrosyl chloride, NOCI, decomposes to NO and Cl,...Ch. 12 - Hydrogen gas and iodine gas react via the...Ch. 12 - 12.31 A system consisting of 0.100 mole of oxygen...Ch. 12 - Prob. 12.32PAECh. 12 - Prob. 12.33PAECh. 12 - 1’he reaction in Exercise 12.33 was repeated. This...Ch. 12 - In the reaction in Exercise 12.33, another trial...Ch. 12 - The experiment in Exercise 12.33 was redesigned so...Ch. 12 - Again the experiment in Exercise 12.33 was...Ch. 12 - At a particular temperature, the equilibrium...Ch. 12 - A student is simulating the carbonic acid—hydrogen...Ch. 12 - Because carbonic acid undergoes a second...Ch. 12 - Because calcium carbonate is a sink for CO32- in a...Ch. 12 - 12.42 The following reaction is in equilibrium in...Ch. 12 - Prob. 12.43PAECh. 12 - Prob. 12.44PAECh. 12 - The following equilibrium is established in a...Ch. 12 - Write the K_, expression for each of the following...Ch. 12 - Prob. 12.47PAECh. 12 - calculate the molar solubility of the following...Ch. 12 - 12.49 The Safe Drinking Water Act of 1974...Ch. 12 - In Exercise 12.49, what is the allowed...Ch. 12 - Prob. 12.51PAECh. 12 - Because barium sulfate is opaque to X-rays, it is...Ch. 12 - The ore cinnabar (HgS) is an important source of...Ch. 12 - Prob. 12.54PAECh. 12 - From the solubility data given for the following...Ch. 12 - The solubility of magnesium fluoride, MgF2, in...Ch. 12 - Solid Na2SO4 is added slowly to a solution that is...Ch. 12 - Will a precipitate of Mg(OH)2 form when 25.0 mL of...Ch. 12 - Use the web to look up boiler scale and explain...Ch. 12 - Prob. 12.60PAECh. 12 - Prob. 12.61PAECh. 12 - 12.62 Write the formula of the conjugate acid of...Ch. 12 - 12.63 For each of the following reactions,...Ch. 12 - What are the products of each of the following...Ch. 12 - Prob. 12.65PAECh. 12 - Prob. 12.66PAECh. 12 - 12.67 Hydrofluoric acid is a weak acid used in the...Ch. 12 - The pH of a 0.129 M solution of a weak acid, HB,...Ch. 12 - Calculate the pH of a 0.10 M solution of propanoic...Ch. 12 - Find the pH of a 0.115 M solution of NH3(aq).Ch. 12 - Acrylic acid is used in the polymer industry in...Ch. 12 - Prob. 12.72PAECh. 12 - Prob. 12.73PAECh. 12 - Prob. 12.74PAECh. 12 - Cyanic acid (HOCN) is a weak acid with AL, = 3.5 X...Ch. 12 - In a particular experiment, the equilibrium...Ch. 12 - Prob. 12.77PAECh. 12 - Prob. 12.78PAECh. 12 - Prob. 12.79PAECh. 12 - Prob. 12.80PAECh. 12 - Prob. 12.81PAECh. 12 - Prob. 12.82PAECh. 12 - Prob. 12.83PAECh. 12 - Prob. 12.84PAECh. 12 - 12.85 In the figure, orange fish are placed in one...Ch. 12 - For the system in the preceding problem, show the...Ch. 12 - Prob. 12.87PAECh. 12 - Which of the following is more likely to...Ch. 12 - Prob. 12.89PAECh. 12 - Prob. 12.90PAECh. 12 - In the following equilibrium in a closed system,...Ch. 12 - Consider the following system:...Ch. 12 - The decomposition of NH4HS , NH4HS(s)NH3(g)+H2S(g)...Ch. 12 - You are designing a process to remove carbonate...Ch. 12 - Equal amounts of two gases, A and B3, are placed...Ch. 12 - Prob. 12.96PAECh. 12 - Prob. 12.97PAECh. 12 - Prob. 12.98PAECh. 12 - Solid CaCO3 ; is placed in a closed container and...Ch. 12 - 12.100 A reaction important in smog formation is...Ch. 12 - 12.101 An engineer working on a design to extract...Ch. 12 - 12.102 A chemical engineer is working to optimize...Ch. 12 - 12.103 Methanol, CH3OH, can be produced by the...Ch. 12 - Prob. 12.104PAECh. 12 - 12.105 Using the kinetic-molecular theory, explain...Ch. 12 - 12.106 The solubility of KCl is 34.7 g per 100 g...Ch. 12 - Prob. 12.107PAECh. 12 - 12.108 A nuclear engineer is considering the...Ch. 12 - 12.109 Copper(II) iodate has a solubility of 0.136...Ch. 12 - 12.110 In Exercise 12.109, what do you predict...Ch. 12 - 12.111 You have three white solids. What...Ch. 12 - Prob. 12.112PAECh. 12 - Prob. 12.113PAECh. 12 - Prob. 12.114PAECh. 12 - Prob. 12.115PAECh. 12 - Prob. 12.116PAECh. 12 - 12.117 The vapor pressure of water at 80.0 °C is...Ch. 12 - Prob. 12.118PAE
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