(a)
Interpretation:
The change in the unit cell is to be determined.
Concept introduction:
Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:
1. The simple cubic unit cell
2. Body-centered unit cell
3. Face-centered unit cell
In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is
(b)
Interpretation:
Whether the coordination number of cadmium changes or not is to be determined. Also, the reason for the change is to be explained.
Concept introduction:
Crystal structure or lattice is the three-dimensional representation of atoms and molecules arranged in a particular manner. The unit cell is the smallest part of the lattice that is repeated in all directions to yield the crystal lattice. There are 3 types of cubic unit cells as follows:
1. The simple cubic unit cell
2. Body-centered unit cell
3. Face-centered unit cell
In the cubic unit cell, atom at the corner is shared by 8 adjacent cells so the contribution of an atom at the corner is
The nearest neighbors of an atom crystallize in a crystal is known as coordination number.
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Chapter 12 Solutions
CHEMISTRY MOLECULAR NATURE OF MATTER
- I have a question about this problem involving mechanisms and drawing curved arrows for acids and bases. I know we need to identify the nucleophile and electrophile, but are there different types of reactions? For instance, what about Grignard reagents and other types that I might not be familiar with? Can you help me with this? I want to identify the names of the mechanisms for problems 1-14, such as Gilman reagents and others. Are they all the same? Also, could you rewrite it so I can better understand? The handwriting is pretty cluttered. Additionally, I need to label the nucleophile and electrophile, but my main concern is whether those reactions differ, like the "Brønsted-Lowry acid-base mechanism, Lewis acid-base mechanism, acid-catalyzed mechanisms, acid-catalyzed reactions, base-catalyzed reactions, nucleophilic substitution mechanisms (SN1 and SN2), elimination reactions (E1 and E2), organometallic mechanisms, and so forth."arrow_forwardSolve the spectroarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- Don't used hand raiting and don't used Ai solutionarrow_forward2. 200 LOD For an unknown compound with a molecular ion of 101 m/z: a. Use the molecular ion to propose at least two molecular formulas. (show your work) b. What is the DU for each of your possible formulas? (show your work) C. Solve the structure and assign each of the following spectra. 8 6 4 2 (ppm) 150 100 50 ō (ppm) 4000 3000 2000 1500 1000 500 HAVENUMBERI-11arrow_forwardComplete the spectroscopy with structurearrow_forward
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