Principles of Instrumental Analysis
Principles of Instrumental Analysis
7th Edition
ISBN: 9781305577213
Author: Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher: Cengage Learning
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Chapter 12, Problem 12.8QAP
Interpretation Introduction

(a)

Interpretation:

The density of solution I2 is 0.794gm/cm3 which is present in ethanol. Transmission of 33.2% of the radiation from a Mo Ka is done by using a layer of 1.50 cm. Mass absorption coefficient are 39.2,0.70, 0.00, 1.50 for I, C, H and O respectively. Percentage of I2 present in ethanol is to be determined, neglecting the absorption by alcohol.

Concept introduction:

Formula used for the calculation are-

lnPoP=μMρx

Where,

Po= transmitted beam power

P = incident beam power

µM = mass absorption coefficient

ρ = density

x = sample thickness

μM=W×μ

Where,

μM = mass absorption coefficient of the sample

μ I2 = mass absorption coefficient of I2 W= weight fraction of iodine

Interpretation Introduction

(b)

Interpretation:

Percentage of I2 present in ethanol is to be determined when alcohol is present.

Concept introduction:

Formula used for the calculation are-

lnPoP=μMρx

μM=W×μ

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Which of the following are descriptions of possible starting material for this reaction? H ? trace acid an ester a ketone an imine an aldehyde a carboxylic acid an enamine a primary amine a secondary amine a tertiary amine
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