
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
2nd Edition
ISBN: 9781285074788
Author: Ball
Publisher: CENGAGE L
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Chapter 12, Problem 12.8E
Interpretation Introduction
Interpretation:
Whether the two spin functions
Concept introduction:
For the orthogonality of the two different wavefunctions, the product of the wave functions is integrated over the entire limits. It is expressed by the equation as given below.
Where,
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Given the reaction R+ Q → P, indicate
(A). the rate law with respect to P:
(B). the rate law with respect to R:
(C). the rate law with respect to Q:
d[P]
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d[R]
dt
d[Q]
dt
The reaction for obtaining NO2 from NO and O2 has the rate equation: v = k[NO]2[O2]. Indicate which of the following options is correct.(A). This rate equation is inconsistent with the reaction consisting of a single trimolecular step.(B). Since the overall order is 3, the reaction must necessarily have some trimolecular step in its mechanism.(C). A two-step mechanism: 1) NO + NO ⇄ N2O2 (fast); 2) N2O2 + O2 → NO2 + NO2 (slow).(D). The mechanism must necessarily consist of three unimolecular elementary steps with very similar rate constants.
a. What is the eluent used in the column chromatography here (a “silica plug filtration” is essentially a very short column)?
b. The spectroscopy of compound 5b is described in the second half of this excerpt, including 1H-NMR and 13C-NMR (which you will learn about in CHEM 2412L), MS (which you will learn about later in CHEM 2411L) and IR. One of the IR signals is at 3530 cm-1. What functional group does this indicate might be present in compound 5b?
Chapter 12 Solutions
PHYSICAL CHEMISTRY-STUDENT SOLN.MAN.
Ch. 12 - In the Stern-Gerlach experiment, silver atoms were...Ch. 12 - Prob. 12.2ECh. 12 - Prob. 12.3ECh. 12 - Suppose s=12 for an electron. Into how many parts...Ch. 12 - Using and labels, write two possible...Ch. 12 - List all possible combinations of all four quantum...Ch. 12 - What are the degeneracies of the H atom...Ch. 12 - Prob. 12.8ECh. 12 - a Differentiate between the quantum numbers s and...Ch. 12 - Is the spin orbital 1s for the H atom still...
Ch. 12 - Draw a diagram analogous to Figure 11.15, but now...Ch. 12 - Are mathematical expressions for the following...Ch. 12 - Prob. 12.13ECh. 12 - Prob. 12.14ECh. 12 - a Assume that the electronic energy of Li was a...Ch. 12 - Spin orbitals are products of spatial and spin...Ch. 12 - If 1 and 2 are the individual wavefunctions for...Ch. 12 - Show that the correct behavior of a wavefunction...Ch. 12 - Prob. 12.19ECh. 12 - Why isnt the electron configuration of beryllium,...Ch. 12 - Prob. 12.21ECh. 12 - Write a Slater determinant for the lithide ion,...Ch. 12 - Why does the concept of antisymmetric...Ch. 12 - a Construct Slater determinant wavefunctions for...Ch. 12 - Prob. 12.25ECh. 12 - Prob. 12.26ECh. 12 - Prob. 12.27ECh. 12 - Suppose an electron had three possible values of...Ch. 12 - Using a periodic table or Table 12.1, find the...Ch. 12 - Write an acceptable electron configuration for...Ch. 12 - Prob. 12.31ECh. 12 - Prob. 12.32ECh. 12 - Prob. 12.33ECh. 12 - An anharmonic oscillator has the potential...Ch. 12 - Prob. 12.35ECh. 12 - In a particle-in-a-box having length a, the...Ch. 12 - Prob. 12.37ECh. 12 - Prob. 12.38ECh. 12 - Prob. 12.39ECh. 12 - The Stark effect is the change in energy of a...Ch. 12 - Prob. 12.41ECh. 12 - Prob. 12.42ECh. 12 - Prob. 12.43ECh. 12 - Show that a variation theory treatment of H using...Ch. 12 - Prob. 12.45ECh. 12 - Explain why assuming an effective nuclear charge,...Ch. 12 - Prob. 12.47ECh. 12 - Consider a real system. Assume that a real...Ch. 12 - Prob. 12.49ECh. 12 - Prob. 12.50ECh. 12 - Prob. 12.51ECh. 12 - Prob. 12.52ECh. 12 - State the Born-Oppenheimer approximation in words...Ch. 12 - Prob. 12.54ECh. 12 - Spectroscopy deals with differences in energy...Ch. 12 - Prob. 12.56ECh. 12 - What is the bond order for the lowest excited...Ch. 12 - The helium atom was defined as two electrons and a...Ch. 12 - Explain how we know that the first in equation...Ch. 12 - Prob. 12.60ECh. 12 - Prob. 12.61ECh. 12 - Use molecular orbital arguments to decide whether...Ch. 12 - Prob. 12.63ECh. 12 - Prob. 12.65ECh. 12 - Prob. 12.67ECh. 12 - Prob. 12.68E
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