GEN COMBO CHEMISTRY: ATOMS FIRST; ALEKS 360 2S ACCESS CARD CHEMISTRY:ATOMS FIRST
3rd Edition
ISBN: 9781260020229
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 12, Problem 12.84QP
A CO2 fire extinguisher is located on the outside of a building in Massachusetts. During the winter months, one can hear a sloshing sound when the extinguisher is gently shaken. In the summertime there is often no sound when it is shaken. Explain. Assume that the extinguisher has no leaks and that it has not been used.
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Rank the following compounds most to least acidic:
a)
О
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.OH
flow flow
О
F
F
F
F
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F
b)
Ha
EN-Ha
CI
Ha
F
F CI
Ha
a)
b)
Provide arrows to show the mechanisms and then predict the products of the following acid
base reaction. Use pKas to determine which way the reaction will favor (Hint: the lower pka
acid will want to dissociate)
Дон
OH
Ha
OH
NH2
c)
H
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MATERIALS. Differentiate between interstitial position and reticular position.
Chapter 12 Solutions
GEN COMBO CHEMISTRY: ATOMS FIRST; ALEKS 360 2S ACCESS CARD CHEMISTRY:ATOMS FIRST
Ch. 12.2 - Prob. 12.1WECh. 12.2 - Prob. 1PPACh. 12.2 - Prob. 1PPBCh. 12.2 - The diagram on the left depicts a system at room...Ch. 12.2 - Prob. 12.2.1SRCh. 12.2 - Given the following information for C6F6,...Ch. 12.2 - Prob. 12.2.3SRCh. 12.2 - Using the result from question 12.2.3 and another...Ch. 12.3 - Prob. 12.2WECh. 12.3 - When silver crystallizes, it forms face-centered...
Ch. 12.3 - The density of sodium metal is 0.971 g/cm3 and the...Ch. 12.3 - Nickel has a face-centered cubic unit cell with an...Ch. 12.3 - A metal crystallizes in a body-centered cubic unit...Ch. 12.4 - How many of each ion are contained within a unit...Ch. 12.4 - Referring to Figure 12.23, determine how many of...Ch. 12.4 - Referring to Figure 12.23, determine how many of...Ch. 12.4 - Prob. 3PPCCh. 12.4 - The edge length of the NaCl unit cell is 564 pm....Ch. 12.4 - Prob. 4PPACh. 12.4 - NiO also adopts the face-centered cubic...Ch. 12.4 - The metal iridium (Ir) crystallizes with a...Ch. 12.4 - Prob. 5PPACh. 12.4 - Copper crystallizes in a face-centered cubic...Ch. 12.4 - Given that the diameter and average mass of a...Ch. 12.5 - (a) Calculate the amount of heat deposited oil the...Ch. 12.5 - Calculate the amount of energy (in kilojoules)...Ch. 12.5 - Determine the final state and temperature of 100 g...Ch. 12.5 - Prob. 6PPCCh. 12.5 - How much energy (in kilojoules) is required to...Ch. 12.5 - Prob. 12.5.2SRCh. 12.6 - Using the following phase diagram, (a) determine...Ch. 12.6 - Use the following phase diagram to (a) determine...Ch. 12.6 - Prob. 7PPBCh. 12.6 - Prob. 7PPCCh. 12.6 - Prob. 12.6.1SRCh. 12.6 - Prob. 12.6.2SRCh. 12 - Prob. 12.1KSPCh. 12 - Prob. 12.2KSPCh. 12 - Prob. 12.3KSPCh. 12 - Prob. 12.4KSPCh. 12 - Explain why liquids, unlike gases, are virtually...Ch. 12 - What is surface tension? What is the relationship...Ch. 12 - Prob. 12.3QPCh. 12 - Prob. 12.4QPCh. 12 - Prob. 12.5QPCh. 12 - Prob. 12.6QPCh. 12 - Prob. 12.7QPCh. 12 - Why does the viscosity of a liquid decrease with...Ch. 12 - Why is ice less dense than water?Ch. 12 - Prob. 12.10QPCh. 12 - Prob. 12.11QPCh. 12 - Prob. 12.12QPCh. 12 - Prob. 12.13QPCh. 12 - Predict which of the following liquids has greater...Ch. 12 - Prob. 12.15QPCh. 12 - Vapor pressure measurements at several different...Ch. 12 - The vapor pressure of liquid X is lower than that...Ch. 12 - Prob. 12.18QPCh. 12 - Prob. 12.19QPCh. 12 - Define the following terms: crystalline solid,...Ch. 12 - Prob. 12.21QPCh. 12 - Classify the solid states in terms of crystal...Ch. 12 - Prob. 12.23QPCh. 12 - Define X-ray diffraction. What are the typical...Ch. 12 - Prob. 12.25QPCh. 12 - What is the coordination number of each sphere in...Ch. 12 - Calculate the number of spheres that would be...Ch. 12 - Prob. 12.28QPCh. 12 - Barium metal crystallizes in a body-centered cubic...Ch. 12 - Prob. 12.30QPCh. 12 - Europium crystallizes in a body-centered cubic...Ch. 12 - Crystalline silicon has a cubic structure. The...Ch. 12 - Prob. 12.33QPCh. 12 - Prob. 12.34QPCh. 12 - Prob. 12.35QPCh. 12 - Prob. 12.36QPCh. 12 - Shown here is a zinc oxide unit cell. What is the...Ch. 12 - Describe and give examples of the following types...Ch. 12 - Prob. 12.39QPCh. 12 - A solid is hard, brittle, and electrically...Ch. 12 - A solid is soft and has a low melting point (below...Ch. 12 - Prob. 12.42QPCh. 12 - Which of the following are molecular solids and...Ch. 12 - Prob. 12.44QPCh. 12 - Prob. 12.45QPCh. 12 - What is a phase change? Name all possible changes...Ch. 12 - What is the equilibrium vapor pressure of a...Ch. 12 - Use any one of the phase changes to explain what...Ch. 12 - Define the following terms: (a) molar heat of...Ch. 12 - Prob. 12.50QPCh. 12 - What can we learn about the intermolecular forces...Ch. 12 - The greater the molar heat of vaporization of a...Ch. 12 - Prob. 12.53QPCh. 12 - A closed container of liquid pentane (bp = 36.1C)...Ch. 12 - What is critical temperature? What is the...Ch. 12 - Prob. 12.56QPCh. 12 - How do the boiling points and melting points of...Ch. 12 - Prob. 12.58QPCh. 12 - Prob. 12.59QPCh. 12 - Prob. 12.60QPCh. 12 - Which of the following phase transitions gives off...Ch. 12 - Prob. 12.62QPCh. 12 - Prob. 12.63QPCh. 12 - Calculate the amount of heat (in kilo joules)...Ch. 12 - Prob. 12.65QPCh. 12 - The molar heats of fusion and sublimation of lead...Ch. 12 - Prob. 12.67QPCh. 12 - How is the rate of evaporation of a liquid...Ch. 12 - Explain why steam at 100C causes more serious bums...Ch. 12 - The following compounds, listed with then- boiling...Ch. 12 - Prob. 12.71QPCh. 12 - Prob. 12.72QPCh. 12 - Explain how waters phase diagram differs from...Ch. 12 - The blades of ice skates are quite thin, so the...Ch. 12 - A length of wire is placed on top of a block of...Ch. 12 - Prob. 12.76QPCh. 12 - A phase diagram of water is shown. Label the...Ch. 12 - Prob. 12.78QPCh. 12 - Prob. 12.79QPCh. 12 - Prob. 12.80QPCh. 12 - Prob. 12.81QPCh. 12 - Prob. 12.82QPCh. 12 - The average distance between base pairs measured...Ch. 12 - A CO2 fire extinguisher is located on the outside...Ch. 12 - What is the vapor pressure of mercury at its...Ch. 12 - Prob. 12.86QPCh. 12 - The liquid-vapor boundary line in the phase...Ch. 12 - Prob. 12.88QPCh. 12 - Prob. 12.89QPCh. 12 - A student is given four solid samples labeled W,...Ch. 12 - Prob. 12.91QPCh. 12 - The diagram shows a kettle of boiling water....Ch. 12 - The south pole of Mars is covered with solid...Ch. 12 - The properties of gases, liquids, and solids...Ch. 12 - The standard enthalpy of formation of gaseous...Ch. 12 - Prob. 12.96QPCh. 12 - Under the same conditions of temperature and...Ch. 12 - The distance between Li+ and Cl is 257 pm in solid...Ch. 12 - Heat of hydration, that is, the heat change that...Ch. 12 - The fluorides of the second period elements and...Ch. 12 - Calculate the H for the following processes at...Ch. 12 - Prob. 12.102QPCh. 12 - Prob. 12.103QPCh. 12 - Ozone (O3) is a strong oxidizing agent that can...Ch. 12 - A sample of limestone (CaCO3) is heated in a...Ch. 12 - Carbon and silicon belong to Group 4A of the...Ch. 12 - Prob. 12.107QPCh. 12 - A 1.20-g sample of water is injected into an...Ch. 12 - What are the advantages of cooking the vegetable...Ch. 12 - A quantitative measure of how efficiently spheres...Ch. 12 - The phase diagram of helium is shown. Helium is...Ch. 12 - The phase diagram of sulfur is shown. (a) How many...Ch. 12 - Prob. 12.113QPCh. 12 - Argon crystallizes in the face-centered cubic...Ch. 12 - Given the phase diagram of carbon, answer the...Ch. 12 - Prob. 12.116QPCh. 12 - Swimming coaches sometimes suggest that a drop of...Ch. 12 - Prob. 12.118QPCh. 12 - Why do citrus growers spray their trees with water...Ch. 12 - Calcium metal crystallizes in a face-centered...Ch. 12 - A student heated a beaker of cold water (on a...Ch. 12 - The compound diclilorodifluoromethane (CCl2F2) has...Ch. 12 - Iron crystallizes in a body-centered cubic...Ch. 12 - Sketch the cooling curves of water from about 110C...Ch. 12 - Prob. 12.125QPCh. 12 - A sampleof water shows the following behavior as...Ch. 12 - A closed vessel of volume 9.6 L contains 2.0 g of...Ch. 12 - The electrical conductance of copper metal...Ch. 12 - Assuming ideal behavior, calculate the density of...Ch. 12 - Explain why drivers are advised to use motor oil...Ch. 12 - Prob. 12.131QPCh. 12 - Silicon used in computer chips must have an...Ch. 12 - Prob. 12.133QP
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- For each of the following, indicate whether the arrow pushes are valid. Do we break any rules via the arrows? If not, indicate what is incorrect. Hint: Draw the product of the arrow and see if you still have a valid structure. a. b. N OH C. H N + H d. e. f. مه N COHarrow_forwardDecide which is the most acidic proton (H) in the following compounds. Which one can be removed most easily? a) Ha Нь b) Ha Нь c) CI CI Cl Ha Ньarrow_forwardProvide all of the possible resonanse structures for the following compounds. Indicate which is the major contributor when applicable. Show your arrow pushing. a) H+ O: b) c) : N :O : : 0 d) e) Оarrow_forward
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