Elements Of Physical Chemistry
7th Edition
ISBN: 9780198727873
Author: ATKINS, P. W. (peter William), De Paula, Julio
Publisher: Oxford University Press
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Chapter 12, Problem 12.7DQ
Interpretation Introduction
Interpretation:
The reason for why substances with high heat capacities have higher entropies has to be explained.
Concept Introduction:
Heat capacity can be defined as the ratio of the amount of heat transferred to a substance to the corresponding increase in the temperature of the substance. It is represented by the letter
Entropy refers to the thermal energy per unit temperature that is being unavailable to do some mechanical work. It is represented by the letter
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Please explain step by step in detail the reasoning behind this problem/approach/and answer. thank you!
2. Predict the product(s) that forms and explain why it forms. Assume that any necessary catalytic acid is
present.
.OH
HO
H₂N
OH
consider the rate of the reaction
below to be r. Whats the rate after
each reaction?
Br
+ NaCN
CN
+
NaBr
a. Double the concentration of alkyl bromide
b. Halve the concentration of the electrophile & triple concentration of cyanide
c. Halve the concentration of alkyl chloride
Chapter 12 Solutions
Elements Of Physical Chemistry
Ch. 12 - Prob. 12A.1STCh. 12 - Prob. 12A.2STCh. 12 - Prob. 12B.2STCh. 12 - Prob. 12B.3STCh. 12 - Prob. 12B.5STCh. 12 - Prob. 12C.1STCh. 12 - Prob. 12C.3STCh. 12 - Prob. 12C.4STCh. 12 - Prob. 12A.1ECh. 12 - Prob. 12A.2E
Ch. 12 - Prob. 12A.3ECh. 12 - Prob. 12B.1ECh. 12 - Prob. 12B.2ECh. 12 - Prob. 12B.3ECh. 12 - Prob. 12B.4ECh. 12 - Prob. 12B.5ECh. 12 - Prob. 12B.6ECh. 12 - Prob. 12C.4ECh. 12 - Prob. 12.1DQCh. 12 - Prob. 12.2DQCh. 12 - Prob. 12.3DQCh. 12 - Prob. 12.4DQCh. 12 - Prob. 12.5DQCh. 12 - Prob. 12.6DQCh. 12 - Prob. 12.7DQCh. 12 - Prob. 12.8DQCh. 12 - Prob. 12.1PCh. 12 - Prob. 12.3PCh. 12 - Prob. 12.5PCh. 12 - Prob. 12.6PCh. 12 - Prob. 12.8PCh. 12 - Prob. 12.9PCh. 12 - Prob. 12.10PCh. 12 - Prob. 12.11PCh. 12 - Prob. 12.12PCh. 12 - Prob. 12.13PCh. 12 - Prob. 12.14P
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- Predict the organic reactant that is involved in the reaction below, and draw the skeletal ("line") structures of the missing organic reactant. Please include all steps & drawings & explanations.arrow_forwardWhat are the missing reagents for the spots labeled 1 and 3? Please give a detailed explanation and include the drawings and show how the synthesis proceeds with the reagents.arrow_forwardWhat is the organic molecule X of the following acetal hydrolysis? Please draw a skeletal line structure and include a detailed explanation and drawing of how the mechanism proceeds. Please include any relevant information that is needed to understand the process of acetal hydrolysis.arrow_forward
- What are is the organic molecule X and product Y of the following acetal hydrolysis? Please draw a skeletal line structure and include a detailed explanation and drawing of how the mechanism proceeds. Please include any relevant information that is needed to understand the process of acetal hydrolysis.arrow_forwardAt 300 K, in the decomposition reaction of a reactant R into products, several measurements of the concentration of R over time have been made (see table). Without using graphs, calculate the order of the reaction. t/s [R]/(mol L-1) 0 0,5 171 0,16 720 0,05 1400 0,027arrow_forwardPredict the organic products that form in the reaction below, and draw the skeletal ("line") structures of the missing organic products. Please include all steps & drawings & explanations.arrow_forward
- What are the missing reagents for the spots labeled 1 and 3? Please give a detailed explanation and include the drawings and show how the synthesis proceeds with the reagents.arrow_forwardWhat are the products of the following acetal hydrolysis? Please draw a skeletal line structure and include a detailed explanation and drawing of how the mechanism proceeds. Please include any relevant information that is needed to understand the process of acetal hydrolysis.arrow_forwardWhat would happen if you added the HCI to the Grignard reagent before adding benzophenone? Draw a reaction mechanism to support your answer.arrow_forward
- At 300 K, in the decomposition reaction of a reactant R into products, several measurements of the concentration of R over time have been made (see table). Calculate the order of the reaction. t/s [R]/ (mol L-1) 0 0,5 171 0,16 720 0,05 1400 0,027arrow_forwardWrite the correct IUPAC names of the molecules in the picturearrow_forwardHow many grams of solid NaCN have to be added to 1.5L of water to dissolve 0.18 mol of Fe(OH)3 in the form Fe(CN)63 - ? ( For simplicity, ignore the reaction of CN - ion with water) Ksp for Fe(OH)3 is 2.8E -39, and Kform for Fe(CN)63 - is 1.0E31arrow_forward
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