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(a)
Interpretation:
The equivalence volume of
Concept introduction:
Volumetric principle:
The volume and concentration of unknown solution is determined by it is titrate with known volume and concentration solution.
The volume and concentration of unknown solution is required equivalent volume and concentration of known solution in the volumetric titration.
Where,
(a)
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Answer to Problem 12.6P
The volume of solution at equivalent point is
Explanation of Solution
To determine the volume of solution at equivalent point in
Given,
Volume of known solution is
Concentration of known solution is
Concentration of
According to the volumetric principle,
The given values are plugged in above equation to give a volume of solution at equivalent point in
The equivalence volume of
(b)
Interpretation:
The concentration of
Concept introduction:
Molarity:
The number of moles of solute present in liter of volume of solution is given by molarity.
(b)
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Answer to Problem 12.6P
The concentration of
Explanation of Solution
To determine the concentration of
Given,
Equivalent point in
Volume of solution is
Where,
Total volume of solution is,
The concentration of
The fraction remaining and volume of solution are plugged in above equation to give the concentration of
The concentration of
(c)
Interpretation:
At
Concept Information:
Degree of dissociation:
The ratio of mole of reactant that underwent to dissociating to mole of initial reactant is known as degree of dissociation.
In EDTA the degree of dissociation is,
If pH is fixed, the degree of dissociation
Where,
(c)
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Explanation of Solution
To give the degree of dissociation
Given,
From the standard data table the
At
(d)
Interpretation:
The conditional formation constant should be calculated.
Concept Information:
Degree of dissociation:
The ratio of mole of reactant that underwent to dissociating to mole of initial reactant is known as degree of dissociation.
In EDTA the degree of dissociation is,
If pH is fixed, the degree of dissociation
Where,
(d)
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Explanation of Solution
To calculate the conditional formation constant
Given,
The formation constant
From the standard data table the
The degree of dissociation and formation constant are plugged ion above equation to give conditional formation constant.
The conditional formation constant was calculated.
(e)
Interpretation:
At
Concept Information:
Conditional Formation Constant:
In the reaction of metal with ligand, the equilibrium constant is called as formation constant or the stability constant.
The formation constant for above complex reaction is,
Where,
If pH is constant, the degree of dissociation
Where,
(e)
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Answer to Problem 12.6P
At
Explanation of Solution
To calculate the concentration of
Given,
Total volume of solution is
Concentration of titrants is
The concentration of
We know,
The calculated concentration of
At
(f)
Interpretation:
At
Concept Information:
Conditional Formation Constant:
In the reaction of metal with ligand, the equilibrium constant is called as formation constant or the stability constant.
The formation constant for above complex reaction is,
Where,
If pH is constant, the degree of dissociation
Where,
(f)
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Answer to Problem 12.6P
At
Explanation of Solution
To calculate the concentration of
Given,
Total volume of
Concentration of
The concentration of
The concentration of
We know,
The calculated concentrations of
At
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Chapter 12 Solutions
Quantitative Chemical Analysis
- Predict the major products of the following organic reaction: O O + A ? Some important notes: • Draw the major product, or products, of the reaction in the drawing area below. • If there aren't any products, because no reaction will take place, check the box below the drawing area instead. • Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers. Explanation Check Click and drag to start drawing a structure. eserved. Terms of Use | Privacy Center >arrow_forward(EXM 2, PRBLM 3) Here is this problem, can you explain it to me and show how its done. Thank you I need to see the work for like prbl solving.arrow_forwardcan someone draw out the reaction mechanism for this reaction showing all bonds, intermediates and side products Comment on the general features of the 1H-NMR spectrum of isoamyl ester provided belowarrow_forward
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- Don't used hand raiting and don't used Ai solution and correct answerarrow_forwardH R Part: 1/2 :CI: is a/an electrophile Part 2 of 2 Draw the skeletal structure of the product(s) for the Lewis acid-base reaction. Include lone pairs and formal charges (if applicable) on the structures. 4-7: H ö- H Skip Part Check X :C1: $ % L Fi Click and drag to start drawing a structure. MacBook Pro & ㅁ x G 0: P Add or increase positive formal cha Save For Later Submit ©2025 McGraw Hill LLC. All Rights Reserved. Terms of Use | Privacy Centearrow_forwardDraw the friedel-crafts acylation mechanism of m-Xylenearrow_forward
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