The decomposition of NH 4 HS, NH 4 HS ( s ) ⇄ NH3 ( g ) + H 2 S ( g ) is an endothermic process. Using Le Chatelier's principle, explain how increasing the temperature would affect the equilibrium. If more NH 4 HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH 3 is placed in the flask? What will happen to the pressure of NH3 if some H 2 S is removed from the flask?
The decomposition of NH 4 HS, NH 4 HS ( s ) ⇄ NH3 ( g ) + H 2 S ( g ) is an endothermic process. Using Le Chatelier's principle, explain how increasing the temperature would affect the equilibrium. If more NH 4 HS is added to a flask in which this equilibrium exists, how is the equilibrium affected? What if some additional NH 3 is placed in the flask? What will happen to the pressure of NH3 if some H 2 S is removed from the flask?
Solution Summary: The author explains the Le-Chatelier principle that if there is any change in the state of equilibrium, the reaction favors forward direction.
is an endothermic process. Using Le Chatelier's principle, explain how increasing the temperature would affect the equilibrium. If more NH4HS is added to a flask in which this equilibrium exists, how is the equilibrium affected?
What if some additional NH3 is placed in the flask?
What will happen to the pressure of NH3 if some H2S is removed from the flask?
9:27 AM Tue Mar 4
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Problem 64 of 15
#63%
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Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product
structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s).
Be sure to account for all bond-breaking and bond-making steps.
0:0
0:0
:0:
N.
:0:
:O
:0:
H
H.
:0:
Select to Add Arrows
O
:0:
H
O
:0:
0:0.
S.
H
Select to Add Arrows
S
:0:
:0:
H
H
Order the following organic reactions by relative rate. That is, select '1' next to the reaction that will have the fastest initial rate, select '2' next to the reaction
that will have the next fastest initial rate, and so on. If two reactions will have very similar initial rates, you can select the same number next to both.
If a reaction will have zero or nearly zero initial rate, don't select a number and check the box in the table instead.
Note: the "Nu" in these reactions means "a generic nucleophile."
ملی
CI
:Nu
2
он
3
H
Reaction
Relative Rate
(Choose one) ▼
Nu
:CI:
zero or nearly zero
Nu
:Nu
bi
(Choose one)
zero or nearly zero
: Nu
لی
Nu
:H
(Choose one)
zero or nearly zero
9:12 AM Tue Mar 4
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Problem 38 of 15
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Curved arrows are used to illustrate the flow of electrons. Use the reaction conditions provided and follow
the arrows to draw the product formed in this reaction or mechanistic step(s).
Include all lone pairs and charges as appropriate. Ignore inorganic byproducts.
Br2
FeBrз
H
(+)
Br:
H
: Br----FeBr3
く
a
SU
00
nd
e
Chapter 12 Solutions
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