(a) Interpretation: How the given epoxide can be produced from an alkene is to shown. Concept introduction: An epoxide can be produced from an alkene using a peroxyacid ( RCO 3 H ) , also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

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Answer 1

Question

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <

2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity

Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

Answer 2

Question

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

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Answer 3

Question

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

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Answer 4

Question

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

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Answer 5

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Answer 6

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Answer 7

Chapter 12, Problem 12.48P

Interpretation Introduction

(a)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene. The stereochemistry that describes the C=C bond remains the same in the product.

Answer 8

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Answer 9

Interpretation Introduction

(b)

Interpretation:

How the given epoxide can be produced from an alkene is to shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Answer 10

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Answer 11

Interpretation Introduction

(c)

Interpretation:

How the given epoxide can be produced from an alkene is to be shown.

Concept introduction:

An epoxide can be produced from an alkene using a peroxyacid (RCO3H), also called a peracid. Treatment of an alkene with a peroxyacid (or peracid) produces an epoxide. The reagent MCPBA, a peroxyacid, can form an epoxide in a one-step reaction with an alkene.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 12 - Prob. 12.1P Ch. 12 - Prob. 12.2P Ch. 12 - Prob. 12.3P Ch. 12 - Prob. 12.4P Ch. 12 - Prob. 12.5P Ch. 12 - Prob. 12.6P Ch. 12 - Prob. 12.7P Ch. 12 - Prob. 12.8P Ch. 12 - Prob. 12.9P Ch. 12 - Prob. 12.10P

Solution Summary: The author explains how an epoxide can be produced from an alkene using a peroxyacid.

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Chapter 12 Solutions